姓    名:林梅金

职    称:研究员(博士生导师)

学    历:博士

职    务:超分子结构与材料研究所所长、

               材料科学与工程学院副院长

电    话:22866143/13850162299

专    业:有机化学、物理化学、无机化学

电子邮件:meijin_lin@fzu.edu.cn

研究方向:超分子功能材料

网    页:http://supramol.fzu.edu.cn/

课题组网页微信二维码

  

教育工作经历

教育经历

2007.04-2010.02       法国斯特拉斯堡大学攻读博士学位,导师:Mir Wais Hosseini教授;

2000.09-2003.07       福州大学化学化工学院无机化学专业攻读硕士学位,导师:王俊东教授和杨素苓教授;

1996.09-2000.07       福州大学化学化工学院国家理科化学基地班。

工作经历

2014.06-至今           福州大学化学学院,研究员、博士生导师;

2012.05–2014.05      福州大学化学化工学院,校聘副教授、研究员;

2010.03– 2011.12     德国维尔茨堡大学Frank Würthner教授课题组,博士后;

2007.04-2010.02       法国斯特拉斯堡大学Mir Wais Hosseini教授课题组,玛丽居里ESR学者;

2000.09-2007.03       福州大学化学化工学院,助教、讲师。

 

 教学简介

高等结构化学、有机化学、有机化学实验以及超分子化学等

 

科研简介(详见

我们课题组目前主要致力于超分子功能材料研究,主要在超分子组装的基础上探索和构建先进的功能体系,打造一个以新一代功能材料为特色的系统工程。近几年来,在国家自然科学青年基金和面上项目、教育部博士点基金、福建省新世纪人才计划、福建省自然科学基金、结构化学国家重点实验室开放基金、能源与环境光催化国家重点实验室开放基金等研究项目的支持下,针对超分子功能体系多尺度功能调控的关键科学问题,从有机功能分子(特别是缺电子型稠环酰亚胺、紫精、核黄素等染料分子)的分子设计入手,研究其超分子作用与超分子组装,探讨其结构与谱学性质、主客体化学以及光诱导电子转移等性能间的内在联系,总结上述性能的调控规律,并探索其在一些高新技术领域(如催化、光催化、能源电池等领域)应用,取得一些重要研究进展。迄今为止,已经在本学科相关国际期刊,包括Angew. Chime. Int. Ed.Chem. Sci.、ChemCommun.Inorg. Chem.Cryst. Growth Des.等上发表文章50余篇,并获授权国家发明专利3项。

  

课题组简介

目前,课题组拥有一支中青年科研人员为骨干,思维活跃、积极向上、富有创新精神的科研团队,现有5名留学法国、德国、日本等国家,具有有机化学、超分子化学、结构化学和理论化学等研究背景的专职教师,以及20名左右的硕、博士生。

                   

欢迎大家加入我们课题组!! 

(招收有机化学、无机化学、物理化学、材料化学硕士生、博士生和博士后)

 

授之以鱼,不如授之以渔

Give a man a fish and you feed him for a day. Teach a man to fish and you feed him for a lifetime.

 

 学术兼职

 福州大学超分子结构与材料研究所所长,同时兼任学院学术委员会委员、外事负责人和国际化办学负责人(详见)。

 

主持科研项目

(1)国家自然科学基金面上项目:新型阴离子−π可见光催化体系的构建与性能调控(65.0万,2020.01-2023.12),在研;

(2)国家自然科学基金面上项目:新型双活性位点手性可见光催化剂的设计合成和结构调控(77.0万,2016.01-2019.12),在研;

(3)能源与环境光催化国家重点实验室开放基金:面向不对称合成的新型手性光催化剂设计合成和结构调控(3.0万,2017.01-2019.12),在研;

(4)福建省新世纪人才计划:新型双活性位点手性可见光催化剂的设计合成和性能研究(9.0万,2016.01-2019.12),在研;

(5)国家自然科学基金青年项目:D-A型钌联吡啶/苝酰亚胺超分子笼的构筑及其光催化有机反应性能(25.0万,2013.01-2015.12),已结题;

(6)教育部博士点基金:D-A型钌联吡啶/苝酰亚胺超分子笼的组装及其光催化有机反应性能(4.0万,2013.01-2015.12),已结题;

(7)福建省自然科学基金:D-A型笼状超分子光催化剂的构筑及其在有机合成中的应用(5.0万,2014.01-2016.12),已结题;

(8)结构化学国家重点实验室开放基金:D-A型钌基超分子笼的合成、结构及其可见光催化有机反应性能(5.0万,2014.01-2016.12),已结题;

(9)福州大学科技发展基金:D-A型超分子光催化剂的构筑及其在有机合成中的应用(3.5万,2012.06-2015.05),已结题;

(10)福州大学人才基金:新型有机合成用超分子光催化剂的设计与合成(10.0万,2012.07-2015.06),已结题;

 

代表性论文

Independent research at FZU since 2012

 

(64)L. Li, Y. J. Hong, D. Y. Chen, W. C. Xiao, M. J. Lin*, Anion-π Interactions in Lithium-Organic Redox Flow Batteries, Chem.Commun, 2019, 55, 2364-2367. PDF

(63)Z. Xiang, Y. B. Shan, T. Li, C. C. Huang*, X. H. Huang, M. J. Lin, Four isostructural lanthanide(III) coordination compounds based on a new N-oxydic pyridyl naphthalenediimide ligand: synthesis and characterization, Acta Crystallogr. C, 2019, C75, 38-45. PDF

(62)Y. Chen, Z. C. Liu, M. J. Lin, Q. L. Lin, B. H. Tong, D. Y. Chen*, Selectivity enhancement of quaternized poly(arylene ether ketone) membranes by ion segregation for vanadium redox flow batteries, SCI Chin. Chem., 2019, 62, ASAP. PDF

(61)M. H. Li, M. H. You, J. Y. Zhang, W. C. Xiao, M. J. Lin*, A Bicontinuous Donor-Acceptor Hybrid Heterostructure Based on Coordination and Cation-π Interactions, CrystEngComm, 2018, 20, 7795-7801. PDF

(60)M. H. You, X. Fang, M. J. Lin*, Synthesis, Structure, and Optical Limiting Properties of an Axial Substituted Bis(8-oxide quinoline)zirconium Phthalocyanine, Chin. J. Struc. Chem., 2018, 37, 1971-1978. PDF

(59)L. Li, Y. J. Hong, Y. Lin, W. C. Xiao, M. J. Lin*, An Electron-Deficient Nanosized Polycyclic Aromatic Hydrocarbon with Enhanced Anion-π Interactions, Chem.Commun, 2018, 54, 11941-11944. PDF

(58)J. J. Liu, Z. Xiang, Y. F. Guan, C. C. Huang*,  M. J. Lin*, Two novel donor-acceptor hybrid heterostructures with enhanced visible-light photocatalytic properties, Dalton Trans., 2018, 47, 12041-12045. PDF

(57)L. Li, H. X. Gong, D. Y. Chen,  M. J. Lin*, Stable Bifunctional Perylene Imide Radicals for High-Performance Organic-Lithium Redox-Flow Batteries, Chem. Eur. J., 2018, 24,  13188-13196.(PDF

(56)H. X. Gong, Z. Cao, S. H. Liao,  M. J. Lin*, Photoexcited Perylene Diimide Radical Anions for the Reduction of Aryl Halides: A Bay-substituent Effects, Org. Chem. Front., 2018, 5, 2296-2302.(PDF 

(55)J. J. Liu, T. Liu, S. B. Xia, C. X. He, F. X. Cheng, M. J. Lin*, C. C. Huang*, Cocrystals of naphthalene diimide with naphthalene derivatives: A facile approach to tune the luminescent properties, Dyes Pigments, 2018, 149, 59-64(PDF

(54)L. Li, Y. J. Hong, D. Y. Chen*, M. J. Lin*, Molecular Engineering of Perylene Imides for High-Performance Lithium Batteries: Diels-Alder Extension and Chiral Dimerization, Chem. Eur. J., 2017, 23, 16612-16620. (PDF

(53)L. Li, Y. J. Hong, D. Y. Chen*, M. J. Lin*, A Laterally Extended Perylene Hexacarboxylate via Diels-Alder Reaction for High-Performance Organic Lithium-Ion Batteries, Electrochim. Acta., 2017, 254, 255-261.(PDF

(52)J. J. Liu, Y. B. Shan, W. X. Dai, C. C. Huang*, M. J. Lin*, Assembly of donor-acceptor hybrid heterostructures based on iodoplumbates and viologen coordination polymers, Dalton Trans., 2017, 46, 11556-11560.(PDF

(51)X. Fang, H. Ke, L. Li, M. J. Lin*, Structural Insights into the Aggregation-Induced Emission Mechanism of Naphthalene Diimide Solids, Dyes Pigments, 2017, 145, 469-475.(PDF

(50)J. J. Liu, Y. F. Guan, L. Li, Y. Chen, W. X. Dai, C. C. Huang, M. J. Lin*, Construction of Bicontinuous Hybrid Heterojunctions at the Molecular Level by Inserting Inorganic Nanowires into Porous Metal-Organic Frameworks,  ChemCommun., 2017, 53, 4481-4484.(PDF

(49)J. J. Liu, Y. B. Shan, C. R. Fan, M. J. Lin*, C. C. Huang, W. X. Dai, Encapsulating naphthalene in an electron deficient MOF to enhance fluorescence for organic amines sensing, Inorg. Chem., 2016, 55, 3680-3684.(PDF

(48)J. J. Liu, Y. F. Guan, M. J. Lin*, C. C. Huang*, W. X. Dai, Anion-mediated Architecture and Photochromism of Rigid Bipyridinium-based Coordination Polymers, Crystal Growth & Design, 2016, 16, 2836-2842.(PDF

(47)Y. Chen, J. J. Liu, C. R. Fan, J. Q. Li, M. J. Lin*, Catassembled generation of naphthalene diimide coordination networks with lone pair-π interactions, SCI Sin. Chem., 2016, 59, 1492-1497.(PDF

(46)J. J. Liu, Y. Chen, M. J. Lin*, C. C. Huang*, W. X. Dai, Two-semiconductive-component Hybrid Coordination Polymers with Controllable Photo-induced Electron-transfer Properties, Dalton Trans., 2016, 45, 6339-6342.(PDF

(45)C. Jiao, Z.-Y. Li, J.-J. Liu, M.-J. Lin*, C.-C. Huang, Syntheses and structures of two discrete supramolecular complexes based on 1, 4-diacyl-thiosemicarbazone derivatives, Acta Crystallog. C, 2016, c72, 119-123.(本科生小论文)(PDF

(44)D. Schmidt, M. Son, J. M. Lim, M.-J. Lin, I. Krummenacher, H. Braunschweig, D. Kim, F. Würthner, Perylene Bisimide Radicals and Biradicals: Synthesis and Molecular Properties, Angew. Chem. Int. Ed., 2015, 54, 13980-13984.(PDF

(43)J. J. Liu, Y. F. Guan, Y. Chen, M. J. Lin*, C. C. Huang*, W. X. Dai, The Impact of Lone Pair-π Interactions on Photochromic Properties in 1-D Naphthalene Diimide Coordination Networks, Dalton Trans., 2015, 44, 17312-17317.(PDF

(42)J. J. Liu, Y. F. Guan, M. J. Lin*, C. C. Huang*, W. X. Dai, Luminescent coordination polymer with conjugated Lewis acidic sites for detection of organic amines, Crystal Growth & Design, 2015, 15, 5040-5046.(PDF

(41)J. J. Liu, Y. F. Guan, Y. Chen, M. J. Lin*, C. C. Huang*, W. X. Dai, Mixed-metal metallocavitands: a new approach to tune their electrostatic potentials for a controllable selectivity towards substituted benzene derivatives, Dalton Trans., 2015, 44, 9370-9374.(PDF

(40)J. J. Liu, Y. F. Guan, C. Jiao, M. J. Lin*, C. C. Huang*, W. X. Dai, A Panchromatic Hybrid Crystal of Iodoplumbate Nanowires and J-aggregated Naphthalene Diimides with Long-lived Charge-separated States, Dalton Trans., 2015, 44, 5957-5960.(PDF

(39)H. Ke, C. Jiao, Y. H. Qian, M. J. Lin*, J. Z. Chen*, Naphthalene Diimide Templated Synthesis of Pillar[6]arenes, Chin. J. Chem., 2015, 33, 339-342.(PDF

(38)M. H. You, X. Yuan, X. Fang, M. J. Lin*, Lone Pair-π Interactions in Naphthalene Diimide π-Acid Dyes, Supramol. Chem., 2015, 27, 460–464.(PDF

(37)J. J. Liu, Y. Wang, M. J. Lin*, C. C. Huang*, W. X. Dai, Photogeneration of Two Reduction-active Charge-separated States in a Hybrid Crystal of Polyoxometalates and Naphthalene Diimides, Dalton Trans., 2015, 44, 484-487.(PDF

(36)J. J. Liu, Y. J. Hong, Y. F. Guan, M. J. Lin*, C. C. Huang*, W. X. Dai, Lone Pair-π Interaction-induced Generation of Non-interpenetrated and Photochromic Cuboid 3-D Naphthalene Diimide Coordination Networks, Dalton Trans., 2015, 44, 653-658.(PDF

(35)X. Fang, M. D. Guo, L. J. Weng, Y. Chen, M. J. Lin*, Cooperative Effect of Anion-π and Electrostatic Interactions in NIR Absorbing Phenolate Naphthalene Diimide Conjugates, Dyes Pigments, 2015, 113, 251-256.(PDF

(34)H. Ke, L. J. Weng, S. Y. Chen, M. J. Lin*, J. Z. Chen*, Naphthalene Diimide Cocrystals: A Facile Approach to Tune the Optical Properties, Dyes Pigments, 2015, 113, 318-324.(PDF

(33)J. J. Liu, Y. Wang, Y. J. Hong, M. J. Lin*, C. C. Huang*, W. X. Dai, A Photochromic Naphthalene Diimide Coordination Network Sensitized by Polyoxometalates, Dalton Trans., 2014, 43, 17908-17911.(PDF

(32)J. J. Liu, Y. Wang, S. T. Wu, M. J. Lin*, C. C. Huang*, W. X. Dai, Discrete Polynuclear Manganese Nanorods: Syntheses, Crystal Structures and Magnetic Properties, RSC Adv., 2014, 4, 40958-40963.(PDF

(31)X. Fang, X. Yuan, Y. B. Song, J. D. Wang, M. J. Lin* , Cooperative Lone Pair-π and Coordination Interactions in Naphthalene Diimide Coordination Networks, CrystEngComm, 2014, 16, 9090-9095.(PDF

(30)H. Ke, L. Wang, Y. Chen, M. J. Lin*, J. Z. Chen, Electron-deficient Naphthalene Diimides as Efficient Planar π-Acid Organocatalysts for Selective Oxidative C-C Coupling of 2,6-Di-tertbutylphenol: A Temperature Effect, J. Mol. Catal. A Chem., 2014, 385, 26-30.(PDF

(29)Á. J. Jiménez, M. J. Lin, C. Burschka, J. Becker, V. Settels, B. Engels, F. Würthner*, Structure-property Relationships for 1,7-Diphenoxy-perylene Bisimides in Solution and in the Solid State, Chem. Sci., 2014, 5, 608-619.(PDF

(28)C. C. Huang*, J. J. Liu, Y. Chen, M. J. Lin*, An Electron-deficient Metallocavitand with an Unusual Selectivity Towards Substituted Benzene Derivatives During Co-crystallizations, ChemCommun., 2013, 49, 11512-11514.(PDF

(27)J. Z. Liao, D. C. Chen, F. Li, Y. Chen, N. F. Zhuang, M. J. Lin*, C. C. Huang*, From Achiral Tetrazolate-based Tectons to Chiral Coordination Networks: Effects of Substituents on the Structures and NLO Properties, CrystEngCommun, 2013, 15, 8180-8185.(PDF

(26)M. J. Lin, M. Schulze, K. Radacki, F. Würthner*, Transition Metal Complexes of Axially Chiral Tetrathioether Bay-substituted Perylene Bisimide Dyes, ChemCommun., 2013, 49, 9107-9109.(PDF

(25)X. Fang, J. D. Wang, M. J. Lin*, The Chemical Stabilities of Phthalocyanine Monomers vs. Aggregations, J. Mol. Catal. A Chem., 2013, 372, 100-104.(PDF

(24)H. Y. Yu , X. Fang*, K. K. Zhang , M. J. Lin*, D. Gao, M. D. Huang, J. D. Wang, Hydrothermal Synthesis of Benzothiazole-carboxylic Cadmium(II) Coordination Networks: pH-Controlled Topologies and Compositional Distributions, CrystEngCommun, 2013, 15, 343-348.(PDF

(23)M. J. Lin, Á. J. Jiménez, C. Burschka, F. Würthner*, Bay-substituted Perylene Bisimide Dye with an Undistorted Planar Scaffold and Outstanding Solid State Fluorescence Properties, ChemCommun., 2012, 48, 12050-12052.(PDF)  

 

Before independent research

22M. J. Lin, B. Fimmel, K. Radacki, F. Würthner, Halochromic Phenolate Perylene Bisimides with Unprecedented NIR Spectroscopic Properties, Angew. Chem. Int. Ed., 2011, 50, 10847-10850.

21M. J. Lin, A. Jouaiti, P. Grosshans, N. Kyritsakas, M. W. Hosseini, Molecular tectonics: design of enantiomerically pure helical tubular crystals with controlled channel size and orientation", ChemCommun., 2011, 7635-7637.

(20)M. J. Lin, A. Jouaiti, N. Kyritsakas, M. W. Hosseini, " Molecular tectonics: from 1-D interwoven racemic chains to quadruple stranded helices ", ChemCommun., 2010, 115-117.

(19)M. J. Lin, A. Jouaiti, D. Pocic, N. Kyritsakas, J. M. Planeix, M. W. Hosseini, "Molecular tectonics: tubular crystals with controllable channel size and orientation", ChemCommun.,2010, 112-114.

(18)M. J. Lin, A. Jouaiti, N. Kyritsakas, M. W. Hosseini, "Molecular tectonics: control of interpenetration in cuboid 3-D coordination networks ", CrystEngCommun.,2011, 13, 776-778.

(17)M. J. Lin, A. Jouaiti, N. Kyritsakas, M. W. Hosseini, "Molecular tectonics: chaining cages into a 1-D coordination network", CrystEngCommun., 2010, 12, 67-69.

(16)M. J. Lin, A. Jouaiti, N. Kyritsakas, M. W. Hosseini, "Molecular tectonics: modulation of size and shape of cuboid 3-D coordination networks", CrystEngCommun., 2009, 11, 189-191.

(15)M. J. Lin*, L. Yang, J. D. Wang, “The Spectra and Stabilities of Alkoxyl Subsituted Phthalocyaninatometals: I. the Effect of Axial Coordination Abilities of the Center Metals on their Stabilities in Benzoyl peroxide”, Journal of Molecular Catalysis A: Chemical, 2007, 273, 156-159.

(14)L. Yang, M. J. Lin, X. L. Zhu, X. Z. Xu, J. D. Wang, “Spectra and Stability of α-substituted Phthalocyaninatoirons”, Journal of Molecular Catalysis A: Chemical, 2006, 253, 25-29.

(13)J. D. Wang, M. J. Lin*, S. F. Wu, Y. Lin, “1,15-bis-(2’,2’,4’-trimethyl-3’-pentoxy)phthalocyanine, a trans- form nonperipheral di-substituted phthalocyanine synthesized by the 'cross condensation' method”, Journal of Organometallic Chemistry, 2006, 691, 5074-5076.

(12)M. J. Lin, J. D. Wang, N. S. Chen, J. L. Huang, “Different Conformations of Phthalocyanine Skeletons in A Structure of μ-oxo-bis(phthalocyaninato)iron with Asymmetry Coordination”, Inorganic Chemistry Communications, 2005, 8, 899-901.

(10)M. J. Lin*, X. Fang, M. B. Xu, J. D. Wang, “The Effect of Protonation on the Spectra and Stabilities of Alkoxyl Subsituted Phthalocyaninatometals”, Spectrochimica Acta Part A71, 2008, 1188-1192.

(9)M. J. Lin*, J. D. Wang, “Effect of Non-peripheral Alkyloxy Substituents on the Structure and Spectroscopic Properties of Metal-free Phthalocyanines”, Journal of Molecular Structure, 2007, 837, 284-289.

(9)M. J. Lin*, J. D. Wang, N. S. Chen, J. L. Huang, “Synthesis, Structure, and Spectroscopic Properties of Octa(iso-pentoxy)phthalocyaninatometal complexes”, Z. Anorg. Allg. Chem., 2006, 632, 2315-2320.

(8)M. J. Lin, J. D. Wang, N. S. Chen, “Crystal structure of octaethyloxyphthalo- cyaninatocopper, the overlap affect on the ring skeleton distortion”, Z. Anorg. Allg. Chem. 2005, 631, 1352-1354.

(7)M. J. Lin*, J. D. Wang, N. S. Chen, J. L. Huang, “The crystal structure of pyridines axially substituted octakispentoxyphthalocyaninatocopper: The Molecules Stacked with J-aggregates”, Journal of Coordination Chemistry, 2007, 60, 1479-1484.

(6) M. J. Lin, J. D. Wang, N. S. Chen, J. L. Huang, “A new substituted Phthalocyanine Compound Synthesized by a Convenient Way”, Journal of Coordination Chemistry, 2006, 59(6), 607-611.

(5)M. J. Lin, J. D. Wang, N. S. Chen, J. L. Huang, “Effect of the Trace Water on Electronic Absorption Spectra of Substituted Phthalocyaninatozincs in Solvents”, Acta Phys. -Chim. Sin., 2005, 21(6),677-680. (In Chinese)

(4) M. J. Lin, X. Z. Xu, J. D. Wang, N. S. Chen, J. L. Huang, “Synthesis and crystal structure of 4-Bromo-5-nitrophthalonitrile”, Chinese Journal Synthetic Chemistry, 2005, 13(2), 169-171. (In Chinese)

(3) X. L. Zhu, X. Z. Xu, L. Yang, M. J. Lin, J. D. Wang, J. L. Huang, “Synthesis and photophysical properties of two kinds of substituted phthalocyaninatozinc”, Spectroscopy and Spectral Analysis, 2007, 27(5), 953-956. (In Chinese)

(2) S. F. Wu, X. Z. Xu, M. J. Lin, J. D. Wang, N. S. Chen, J. L. Huang, “Synthesis and UV/Vis spectra of a dialkyloxy substituted phthalocyanine”, Spectroscopy and Spectral Analysis, 2006, 26(3), 513-516. (In Chinese)

(1) X. Z. Xu, J. D. Wang, M. J. Lin, N. S. Chen, J. L. Huang, “Effect of different synthetic methods on constitutes and distribution of phthalocyanines”,Chinese Journal of Inorganic Chemistry, 2005, 21(7), 1009-1014. (In Chinese)

 

获奖情况

2007年获欧盟玛丽居里奖学金(FUMaSSEC项目),2016年入选福建省高校新世纪优秀人才支持计划、第五届福州大学杰出青年教师励志奖和福州大学杨鸿耀奖教奖学金教学优秀奖。

 

 其他

               

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