姓    名:廖赛虎
职    称:教授 (博士生导师)  
学    历:博士
职    务:有机合成与功能福建省高校重点实验室主任
办公室:化学学院嘉锡楼503
电    话:+86-130-43548506
专    业:有机化学,高分子化学
电子邮箱:shliao@fzu.edu.cn
研究方向:有机催化,光催化有机合成,光催化聚合


教育工作经历

教育背景:

  2001-2005:华中科技大学化学系,学士  

  2005-2007:华中科技大学化学系,硕士,导师:龚跃法教授  

  2007-2011:德国马克斯-普朗克煤炭研究所,博士,导师:Prof. Dr. Benjamin List

工作经历:
  2011-2013:中科院上海有机化学研究所,助理研究员,导师:唐勇研究员  

  2013-2016:德国马普煤炭研究所,博士后,导师:Prof. Dr. Benjamin List 

  2016-2019:福州大学化学学院,“闽江学者”特聘教授

  2017.09-至今:福州大学化学学院,教授


教学简介

   有机化学

科研简介

      主要从事有机催化、光催化有机合成、高分子合成等方面工作,先后参与及主持多个科研项目。迄今为止,已在 Acc. Chem. Res., Nat. Commun., J. Am. Chem. Soc., Angew. CHem. Int. Ed. 等国际著名学术期刊上发表论文三十余篇;研究工作受到国际同行积极评价,多篇论文被"NatureChemistry"、"Synform"、"SynFacts"等杂志作为亮点评述。参与编写外文书籍2部,申请中国专利2项,国际专利1项并已获多项授权,另撰写SynFacts评论文章40余篇。2016年入选福建省“闽江学者”特聘教授, 2017年入选海外高层次人才项目,2018年入选高校青年拔尖人才后备项目以及福建省“百人计划”。

     目前主要研究领域:有机催化,光催化有机合成,光催化高分子合成,手性聚合物等。

     课题组常年招收硕士研究生、博士研究生、科研助理和博士后。

     热诚欢迎对有机化学和高分子感兴趣,有科研热情和梦想的同学加入我们!

     一起共筑精彩化学!


社会兼职

    有机合成与功能福建省高校重点实验室主任


科研项目

   1.  福建省百人计划 (2019-2021)

   2.  高校青年拔尖人才后备人才 (2019-2021)  

   3.  海外高层次人才项目 (2017-2020)  

   4.  国家自然科学基金项目青年基金 (2017-2019)

   5.“闽江学者”特聘教授科研启动基金 (2016-2019)


代表性论文


2020:

       4. Xun Zhang, Siping Hu, Qiang Ma, and Saihu Liao,* Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules, Polym. Chem. 2020, DOI:10.1039/D0PY00369G. PDF

       3. Tianxiao Xu, Tianpeng Cao, Mingcheng Yang, Ruting Xu, Xingliang Nie, and Saihu Liao,* Decarboxylative Thiolation of Redox-Active Esters to Thioesters by Merging Photoredox and Copper Catalysis, Org. Lett. 2020, DOI:10.1021/acs.orglett.0c01180. PDF

       2. Tianxiao Xu, Tianpeng Cao, Qingyuan Feng, Shenlin Huang,* and Saihu Liao,* Metal-free dehydrosulfurization of thioamides to nitriles under visible light, Chem. Commun., 2020, DOI:10.1039/d0cc01380c. PDF

       1. Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, Qinggang Wang, and Saihu Liao,* Imidodiphosphorimidate (IDPi) as an Efficient Organocatalyst for Controlled/Living Ring-Opening Polymerization of Lactones, Eur. Polym. J. 2020, 123: 109449. PDF

2019: 

6. Qiang Ma, Xun Zhang, Li Ji, Saihu Liao,* BINOLs as Visible Light Photocatalyst for Metal-Free Atom Transfer Radical Polymerization, Polym. Chem. 2019, 10, 6662-6668. PDF

5. Mingcheng Yang, Tianpeng Cao, Tianxiao Xu, Saihu Liao,* Visible-Light-Induced Deaminative Thioesterification of Amino Acid Derived Katritzky Salts via Electron Donor–Acceptor Complex Formation, Org. Lett. 2019, 21, 8673–8678.

4. Rongbiao Wei, Liang Ge, Hongli Bao, Saihu Liao,* Yajun Li,* Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides, Synthesis, 2019, 51, 4645–4649.

3. Ruting Xu, Tianxiao Xu, Mingcheng Yang, Tianpeng Cao, Saihu Liao,* A Rapid Access to Aliphatic Sulfonyl Fluorides, Nat. Commun. 2019, 10, 3752.

2. Li Ji, Jia-Shuai Liu, Xiao-Yan Wang, Jun-Fang Li, Zhou Chen, Saihu Liao,* Xiu-Li Sun,* Yong Tang, An Efficient and Mild Route to Highly Fluorinated Polyolefins via Copolymerization of Ethylene and 5-Perfluoroalkylnorbornenes, Polym. Chem. 2019, 10, 3604–3609

1. Zhu Cao, Jian-Bo Zhu, Lijia Wang,* Saihu Liao,* Yong Tang, A Synthesis of Multifunctionalized Indoles from [3 + 2] Annulation of 2‑Bromocyclopropenes with Anilines, Org. Lett. 2019, 21, 4097–4100.


2018

1. Hai-Xian Gong, Zhu Cao, Saihu Liao, Mei-Jin Lin*, Photoexcited Perylene Diimide Radical Anions for the Reduction of Aryl Halides: A Bay-substituent Effects, Org. Chem. Front. 2018, 5, 2296–2302.


Selected publications before 2017:

10. Saihu Liao, Markus Leutzsch, Mattia Riccardo Monaco, Benjamin List*, Catalytic Enantioselective Conversion of Epoxides to Thiiranes, J. Am. Chem. Soc. 2016, 138, 5230–5233. (Highlighted by Nature Chemistry and SynFacts)

9. Saihu Liao, Xiu-Li Sun, Yong Tang*, Sidearm Strategy for Catalyst Design Based on Bisoxazolines in the Remote Control of Enantioselection and Related, Acc. Chem. Res. 2014, 47, 2260–2272.

8. Pan Wang, Wen-Jie Tao, Xiu-Li Sun, Saihu Liao* and Yong Tang*, A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis, J. Am. Chem. Soc. 2013, 135, 16849–16852. (Highlighted by SynFacts)

7. Jian-Bo Zhu, Peng Wang, Saihu Liao*, and Yong Tang*, Ylide Hydrolysis in Tandem Reactions: A Highly Z/E-Selective Access to 3-Alkylidene Dihydrobenzofurans and Related Analogues, Org. Lett. 2013, 15, 3054–3057.

6. Jian-Bo Zhu, Peng Wang, Saihu Liao* and Yong Tang*, PPh3-mediated Intramolecular Conjugation of Alkyl Halides with Electron-deficient Olefins: Facile Synthesis of Chromans and Relevant Analogues, Chem. Commun. 2013, 49, 4570–4572.

5. Saihu Liao, Peng Wang, Yong Tang, “Covalent Activations: Ylides” in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications, P. Dalko, Ed., Wiley-VCH & Sons: Weinheim, Germany, 2013. (Book Chapter)

4. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation, Adv. Syn. Catal. 2012, 354, 2363–2367.

3. Benjamin List and Saihu Liao, “The Proline-Catalyzed Mannich Reaction and the Advent of Enamine Catalysis”, in Organic Chemistry–Breakthroughs and Perspectives,K. Ding, L.-X. Dai, Eds., Wiley-VCH: Weinheim, Germany, 2012. (Book Chapter)

2. Saihu Liao, Ilija Čorić, Qinggang Wang, and Benjamin List*, Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation, J. Am. Chem. Soc. 2012, 134, 10765–10768. (Highlighted by SynFacts)

1. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidationof Alkenes with Manganese(III)-Salen Phosphate Complexes, Angew. Chem. Int. Ed. 2010, 49, 628–631. (“Hot Paper”, highlighted by SynFacts)


获奖情况

2018年入选福建省“百人计划

2018年入选福建省高校青年拔尖人才(领军人才后备)项目

2017年入选国家海外高层次人才青年项目

2016年入选福建省“闽江学者”特聘教授


其他

 ***诚聘有机化学或高分子方向博士后和科研助理各2名,待遇从优,有意请发简历至shliao at fzu.edu.cn

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