姓    名: 翁志强
性    别:

 

职    称: 教授, 博导
学    历: 研究生
职    务: 闽江学者特聘教授
电    话: 2286 6121
专    业: 有机化学
电子邮件: zweng@fzu.edu.cn
研究方向: 有机氟化学;金属有机化学

教育工作经历
2010年4月至今: 福州大学化学化工学院, "闽江学者"特聘教授.
2008年1月至2010年3月: 新加坡国立大学化学系(National University of Singapore, Department of Chemistry),校聘研究员[Research Fellow (Academic Staff)],从事教学及开展独立的科研工作 (Teaching and Independent Research).
2006年8月-2007年12月,博士后研究员(Postdoc Fellow), 美国伊利诺大学香槟分校化学系(University of Illinois at Urbana-Champaign), 导师: Prof. John F. Hartwig.
2002年8月-2005年9月,博士后研究员(Postdoc Fellow), 新加坡国立大学化学系, 导师: Prof. Andy T. S. Hor.
1999年7月-2002年7月,获理学博士学位(Ph. D),新加坡国立大学化学系, 导师: Dr. Lai Yoong Goh.
1990年9月-1994年7月&1994年9月-1997年7月,获理学学士&硕士学位(B.S & M.S),福州大学化学系.
 

教学简介
本科生 《有机化学》
本科生《综合实验-有机化学部分》

研究生《高等金属有机化学》
研究生《过度金属在有机化学合成中的应用》
研究生《绿色化学》
 

科研简介
Research Interests:
1. 金属有机氟化合物的合成及对C-F键形成的研究 (Synthesis of Organometallic Fluorine Complexes and Their Reactivity towards C-F Bond Formation)
探索和发现含氟精细化学品的绿色合成和制备方法,发展与医药、农药新品种配套的新型含氟中间体、含氟材料的合成路线和工艺,打造高新技术氟化工产品: (1). 研究新型、高效的氟化试剂、探索氟化反应的新途径、新技术、新工艺;(2). 发展制备含氟芳烃类以及杂环类精细化学品的新方法。


2. 二氧化碳的利用: 金属催化二氧化碳和乙烯偶联制丙烯酸 (Utilization of Carbon Dioxide: Metal-Catalyzed C-C coupling between CO2 and Ethylene)
 

社会兼职
 

科研项目
(1). 福州大学“闽江学者”特聘教授科研启动基金(022318)

(2). 国家自然科学基金(21072030 & 21372044)

(3). 教育部留学回国人员科研启动基金(2012-1707)

(4). 福建省自然科学基金项目(2013J01040)

(5). 教育部博士点基金联合资助课题(No. 20123514110003)
 

代表性论文
2017年:

1. "Trifluoroacetic Anhydride-Promoted Copper(I)-Catalyzed Interrupted Click Reaction: From 1,2,3-Triazoles to 3-Trifluoromethyl-Substituted 1,2,4-Triazinones", Wei Wu, Junwen Wang, Yukang Wang, Yangjie Huang, Yingfei Tan, and Zhiqiang Weng*, Angew. Chem. Int. Ed., 2017, DOI: 10.1002/anie.201705620, accepted.
2. "Synthesis of trifluoromethylthiolated and trifluoromethylselenolated pyrones", Yunxiao Zhang, Ding-Yah Yang,* and Zhiqiang Weng*, Tetrahedron 2017, 73, 3853-3859.
3. "A general method for synthesis of Se-trifluoromethyl esters through Iron-catalyzed trifluoromethylselenolation of acid chlorides", Junwen Wang, Mengjia Zhang, and Zhiqiang Weng*,J. Fluorine Chem. 2017, 193, 24-32.


2016年:

1. "Copper-Mediated Trifluoroacetylation of Arenediazonium Salts with Ethyl Trifluoropyruvate", Wei Wu, Qinli Tian, Taotao Chen, and Zhiqiang Weng*, Chem. Eur. J. 2016, 22, 16455–16458.
2. "Copper-Catalyzed 2,2,2-Trifluoroethylthiolation of Aryl Halides",Shouxiong Chen, Mengjia Zhang, Xuebin Liao,* and Zhiqiang Weng,* J. Org. Chem. 2016, 81, 7993-8000.
3. "Copper-Mediated Decarboxylative Perfluoroalkylation of Vinyl Bromides",Chuyi Wu,Yangjie Huang,Zhongxing Zhang,* and Zhiqiang Weng,* Asian J. Org. Chem. 2016, 5, 1406–1410.
4. "Synthesis of trifluoromethylthiolated pyridinones through the copper-mediated trifluoromethylthiolation of iodopyridinones", Beibei Luo, Yunxiao Zhang, Yi You,* and Zhiqiang Weng,* Org. & Biomol. Chem. 2016, 14, 8615-8622.
5. "Trifluoromethylation of (Hetero)Aryl Iodides and Bromides with Copper(I) Chlorodifluoroacetate Complexes",Xiaoxi Lin, Zhengyu Li, Xiaoyan Han*, and Zhiqiang Weng*, RSC Adv. 2016, 6, 75465-75469.
6. “Copper-Mediated Trifluoromethylthiolation of Heteroaryl Bromides”,Mengjia Zhang, and Zhiqiang Weng*,Adv. Synth. Catal. 2016, 358, 386-394.
7. “Decarboxylative Trifluoromethylating Reagent and Difluorocarbene Precursor: (phen)Cu(O2CCF3) and [(phen)2Cu][O2CCF2Cl]”,Xiaoxi Lin, Chuanqi Hou, Haohong Li, and Zhiqiang Weng*, Chem. Eur. J. 2016, 22, 2075-2084; selected as Hot Paper and highlighted on the ChemistryViews website: http://www.chemistryviews.org/details/ezine/8886621/Copper_Trifluoromethylating_Reagent.html.
8. "A Class of Effective of Decarboxylative Perfluoroalkylating Reagents: [(phen)2Cu](O2CRF)", Yangjie Huang, Manjaly J. Ajitha, Kuo-Wei Huang,* Zhongxing Zhang, and Zhiqiang Weng*, Dalton Trans. 2016, 45, 8468–8474.
9. "Recent advances in trifluoromethylthiolation using nucleophilic trifluoromethylthiolating reagents",Huidong Zheng, Yangjie Huang and Zhiqiang Weng*,Tetrahedron Lett. 2016, 57, 1397-1409.
10. "Copper-mediated trifluoroethoxylation of vinyl bromides", Jianping Ding, Yi You,* and Zhiqiang Weng*,Tetrahedron Lett. 2016, 57, 1724-1727.
11. "A Convenient Process for the Preparation of Heteroaryl Trifluoromethyl Selenoethers", Qinli Tian, and Zhiqiang Weng*, Chin. J. Chem. 2016, 34, 505-510.
12. "Development of Multigram Scale Synthesis of Trifluoromethythiolating Reagent: (bpy)CuSCF3", Yunxiao Zhang, Kangji Gan, and Zhiqiang Weng*, Org. Process Res. Dev. 2016, 20, 799-802.
13. "Copper-mediated effective synthesis of S-trifluoromethyl esters by trifluoromethylthiolation of acid chlorides", Mengjia Zhang, Jinliang Chen, Zhirong Chen*,and Zhiqiang Weng*, Tetrahedron, 2016, 72, 3525-3530.


2015年:

1. “Transition-Metal-Mediated Synthesis of Trifluoroethyl Aryl Ethers” Yangjie Huang,Ronglu Huang,Zhiqiang Weng*, Synlett, 2015, 26, 2327-2331 (Invited SYNPACT Article).
2. “Aryl-BIAN-ligated Silver(I) Trifluoromethoxide Complex” Shouxiong Chen, Yangjie Huang, Xin Fang,* Haohong Li,* Zhongxing Zhang, T. S. Andy Hor, and Zhiqiang Weng*,Dalton Trans. 2015, 44, 19682–19686.
3. “Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides” Ronglu Huang, Yangjie Huang, Xiaoxi Lin, Mingguang Rong, and Zhiqiang Weng*, Angew. Chem. Int. Ed., 2015, 54, 5736-5739.
4. "Alkynyl Trifluoromethyl Selenides Synthesis via Oxidative Trifluoromethylselenolation of Terminal Alkynes", Yuguang Wang, Yi You,* and Zhiqiang Weng*, Org. Chem. Front., 2015, 2, 574–577.
5. “Synthesis of Vinyl Trifluoromethyl Thioethers via Copper-Mediated Trifluoromethylthiolation of Vinyl Bromides”,Yangjie Huang, Jianping Ding, Chuyi Wu, Huidong Zheng,* and Zhiqiang Weng*, J. Org. Chem. 2015, 80, 2912-2917.
6. “A New Method for the Synthesis of Difluormethyl Enol Ethers by O-Difluoromethylation of 1,3-Diones with ClCF2CO2Et” Xiaoxi Lin and Zhiqiang Weng*, Org. Biomol. Chem. 2015, 13, 3432–3437.
7."Transition Metal Complexes Assisted Csp3-F Bond Formation" Xiaoxi Lin, and Zhiqiang Weng*, Dalton Trans. 2015, 44, 2021–2037.
8. “Synthesis of β-Trifluoromethylthio- and Seleno-a,β-Unsaturated Ketones via Copper-Mediated Trifluoromethylthio(seleno)lation” Chuanqi Hou, Xiaoxi Lin, Yangjie Huang, Zhirong Chen,* and Zhiqiang Weng*, Synthesis, 2015, 47, 969-975.
9. “Synthesis of alpa-trifluoroethoxy-substituted ketones” Yuguang Wang, Yi You,* and Zhiqiang Weng*,J. Fluorine Chem. 2015,175,51-59.
10. “Synthesis of vinyl trifluoromethyl selenoethers”,Chuyi Wu, Yangjie Huang, Zhirong Chen,* and Zhiqiang Weng*, Tetrahedron Lett. 2015,56,3838-3841.

2014年:

1."An Improved Protocol for Synthesis of a-Trifluoromethylthio-Substituted Ketones via Copper-Mediated Trifluoromethylthiolation of a-Bromoketones", Yangjie Huang, Xing He, Haohong Li* and Zhiqiang Weng*, Eur. J. Org. Chem. 2014, 7324–7328.
2. "Synthesis of propargylic and allylic trifluoromethyl selenoethers by copper-mediated trifluoromethylselenolation of propargylic chlorides and allylic bromides" Mingguang Rong, Ronglu Huang, Yi You,* and Zhiqiang Weng*, Tetrahedron, 2014, 70, 8872–8878.
3. "Copper-Catalyzed Synthesis of a-Trifluoromethylthio-Substituted Ketones" Yangjie Huang, Xing He, Xiaoxi Lin, Mingguang Rong, and Zhiqiang Weng*, Org. Lett. 2014, 16, 3284-3287.
4. "Direct Palladium-Catalyzed Desulfitative C-C Coupling of Polyfluoroarenes with Arylsulfinate Salts: Water-Accelerated Reactions" Xiaoxi Lin, Yi You,* Zhiqiang Weng*, J. Fluorine Chem. 2014, 165, 76-80.
5. "Efficient C(sp3alkyl)-SCF3 bond Formations via Copper-Mediated Trifluoromethylthiolation of Alkyl Halides" Quanfu Lin, Li Chen, Yangjie Huang, Mingguang Rong, Yaofeng Yuan, and Zhiqiang Weng*, Org. Biomol. Chem. 2014, 12, 5500-5508.
6. “Synthesis of Allylic Trifluoromethyl Thioethers via Copper(I)-Catalyzed Trifluoromethylthiolation of Allylic Bromides” Rong, M.; Huang, R.; Huang, Y.; Han, X.* Weng, Z.* , Eur. J. Org. Chem. 2014, 5010-5016.
7. "Copper-Catalyzed Trifluoromethylselenolation of Aryl and Alkyl Halides: the Silver Effect in Transmetalation" Chen, C.; Hou,C.; Wang,Y.; Hor, T.S.A.*; Weng, Z.*, Org. Lett. 2014, 16, 524.
8. "Synthesis of Cu(I) Trifluoromethylselenates for Trifluoromethylselenolation of Aryl and Alkyl Halides" Chen, C.; Ouyang, L.; Lin, Q.; Liu, Y.; Hou, C.; Yuan, Y.; Weng, Z.*, Chem. Eur. J. 2014, 20, 657.
9. "Copper-Mediated Synthesis of a-Trifluoromethylthio- and Seleno-?a,β-Unsaturated Carbonyl Compounds" Zhu, P.; He, X.; Chen, X.; You, Y. Yuan, Y.; Weng, Z.* Tetrahedron 2014, 70, 672-677.
10."Copper(I) Trifluoromethylthiolate Complex Bearing Triphenylphosphine Ligand for Nucleophilic Trifluoromethylthiolation of Allylic Bromides" Wang, Z.; Tu, Q.; Weng, Z.* J. Organomet. Chem. 2014,751,830-834.

2013年:
1. "Efficient SN2 Fluorination of Primary and Secondary Alkyl Bromides by Cu(I) Fluoride Complexes", Liu, Y.; Chen, C.; Li, H.; Huang, K.W.*; Tan, J.; Weng, Z.* Organometallics, 2013, 32, 6587.
2. "Nucleophilic Trifluoromethylthiolation of Allylic Bromides: A Facile Preparation of Allylic Trifluoromethyl Thioethers" Tan, J.; Zhang, G.; Ouyang, L.; Yuan, Y.; Weng, Z.* Chin. J. Chem. 2013, 31, 921.
3. "An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides", Weng, Z.*; He, W.; Chen, C.; Lee, R.; Tan, D.; Lai, Z.; Kong, D.; Yuan, Y.; Huang, K.-W.* Angew. Chem. Int. Ed., 2013, 52, 1548. (Highlighted by Synfact 2013, 9, 435)
4. "Copper-Catalyzed Trifluoromethylation of Arylsulfinate Salts using an Electrophilic Trifluoromethylation reagent", Lin, X.; Wang, G.; Li, H.; Huang, Y.; He, W.; Ye, D.; Huang, K.-W.*; Yuan, Y.; Weng, Z.* Tetrahedron 2013, 69, 2628.
5. "Synthesis of Polyfluorinated Aryl Ethers via Ligand-free Palladium-Catalyzed C–F Activation of Pentafluorobenzene" Sun, L.; Rong, M.; Kong, D.; Bai, Z.; Yuan, Y.; Weng. Z.* J. Fluorine Chem. 2013, 150, 117.
6. "Preparation of Fluorinated Biaryls Through Direct Palladium-Catalyzed Coupling of Polyfluoroarenes with Aryltrifluoroborates" Fang, X.; Huang, Y.; Chen, X.; Lin, X.; Bai, Z.; Huang, K.-W.*; Yuan, Y.; Weng, Z.* J. Fluorine Chem. 2013, 151, 50.
7. "Room-Temperature Nucleophilic Trifluoromethylthiolation of Benzyl Bromides with (bpy)Cu(SCF3)" Kong, D.; Jiang,* Z.; Xin, S.; Bai, Z.; Yuan, Y.; Weng, Z.* Tetrahedron 2013, 69,6046.

2012年:
1. "Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides", Chen, C.; Weng, Z.*; Hartwig, J. F.* Organometallics, 2012, 31, 8031.
2. "Synthesis of Trifluoromethylated Acetylenes via Copper-Catalyzed Trifluoromethylation of Alkynyltrifluoroborates". Zheng H.; Huang, Y.; Wang, Z.; Li, H.; Huang, K.-W.*; Yuan, Y.; Weng, Z.* Tetrahedron Lett. 2012, 53, 6646.
3. "Room-Temperature Base-Free Copper-Catalyzed Trifluoromethylation of Organotrifluoroborates to Trifluoromethylarenes", Huang Y.; Fang X.; Lin X.; Li H.; He W.; Huang, K.-W.*; Yuan, Y.; Weng Z.* Tetrahedron 2012, 68, 9949.
4. “Mild Copper-Catalyzed Trifluoromethylation of Terminal Alkynes Using an Electrophilic Trifluoromethylating Reagent”, Weng, Z.*; Li H.; He, W.; Yao, L.-F.; Tan, J.; Yuan, Y.; Huang, K.-W.* Tetrahedron 2012, 68, 2527.

2011年:
1. “Cooperative Effect of Silver in Copper Catalyzed Trifluoromethylation of Aryl Iodides Using Me3SiCF3” Weng, Z.*; Lee, R.; Jia, W.; Yuan, Y.; Wang, W.; Huang, K.-W.* Organometallics 2011, 30, 3229.

2010年:
1. “Must N-Heterocyclic Carbene be a Terminal Ligand?” Han, X.; Koh, L. L.; Liu, Z.-P.; Weng, Z.;* Hor, T. S. A.* Organometallics 2010, 29, 2403.
2. “Copper(I) Alkoxide Complexes in the Etherificatiion of Aryl Halides”. Tye, J. W.; Weng, Z.; Hartwig, J. F.* Angew Chem. Int. Ed. 2010, 49, 2185.

2009年:
1. “One-Step Formation of Cyclometallated Au(III) N,S-Heterocyclic Carbene: Crystallographic Analysis.” Han, X.; Koh, L. L.; Weng, Z.*; Hor, T. S. A.* Dalton Trans. 2009, 7248.

2008年:
1. "Unusual Ligand Transformation Mediated by Cr(III): Hydrolytic Disintegration of a [PNP] Hybrid Ligand with CH3CN Insertion”. Teo, S.; Weng, Z.*; Hor, T.S. A.* Organometallics, 2008, 27, 4188.
2. “Enantioselective a-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel.” Liao, X.; Weng, Z. Hartwig. J. F.* J. Am. Chem. Soc. 2008, 130, 195.
3. “Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides.” Tye, J. W.; Weng, Z. Johns, A. M.; Incarvito, C. D.; Hartwig, J. F.* J. Am. Chem. Soc. 2008, 130, 9971.

2007年
1. “Metal Unsaturation and Ligand Hemilability in Suzuki Coupling”. Weng, Z.*; Teo, S.; Hor, T. S. A.* Acc. Chem. Res. 2007, 40, 676.
2. “Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides”. Stambuli, J. P.; Weng, Z.; Incarvito C. D. and Hartwig. J. F.* Angew. Chem. Int. Ed. 2007, 46, 7674.
3. “Chromium(III) Catalysed Ethylene Tetramerization Promoted by Bis(phosphino)amines with an N-Functionalised Pendant”. Weng, Z.* Teo, S.; Hor, T. S. A.* Dalton Trans. 2007, 3493.
4. “A Strange Ni(I)-Ni(0) Binuclear Complex and Its Unexpected Ethylene Oligomerization”. Weng, Z. Teo, S.; Liu, Z.-P.; Hor, T. S. A.* Organometallics 2007, 26, 2950.

2006年及以前:
1. “A Structurally Characterized Ni-Al Methyl-Bridged Complex with Catalytic Ethylene Oligomerization Activity”. Weng, Z. Teo, S.; Koh, L. L.; Hor, T. S. A.* Chem. Commun. 2006, 1319.
2. “Stabilization of Nickel(0) by Hemilabile P,N-Ferrocene Ligands and Their Ethylene Oligomerization Activities”, Weng, Z. Teo, S.; Hor, T. S. A.* Organometallics 2006, 25, 4878.
3. “Ethylene Oligomerization of Coordinatively & Electronically Unsaturated Low-Valent Nickel”. Weng, Z. Teo, S.; Koh, L. L.; Hor, T. S. A.* Angew. Chem. Int. Ed. 2005, 44, 7560.
4. “Homolytic Cleavage and Aggregation Processes in Cyclopentadienylchromium Chemistry”. Weng, Z.; Goh, L. Y.* Acc. Chem. Res. 2004, 37, 187.
5. “Efficient Suzuki-Coupling of Aryl Chlorides Catalyzed by Palladium(0) with P,N-heteroligand and Isolation of Unsaturated Intermediates”, Weng, Z. Teo, S.; Koh, L. L.; Hor, T. S. A.* Organometallics 2004, 23, 4342.
6. “Crystallographic Characterization of a Pd(II) Metallamacrocycle Supported by an Amino-Functionalized Ferrocene and Its Use as an Efficient Suzuki-Coupling Catalyst”, Weng, Z. Teo, S.; Koh, L. L.; Hor, T. S. A.* Organometallics 2004, 23, 3603.
7. “Complexes From Ring Opening of Lawesson’s Reagent and Phosphorus?Phosphorus Coupling”, Weng, Z.; Leong, W. K.; Vittal, J. J.; Goh, L. Y.* Organometallics 2003, 22, 1645.
8. “Phosphinidene- and Phosphido-Bridged Complexes from a ?2-Arylthioxophosphane Cyclopentadienylchromium Complex”, Weng, Z.; Leong, W. K.; Vittal, J. J.; Goh, L. Y.* Organometallics 2003, 22, 1657.
9. “Organometallic-Initiated Cleavage of the Metal Chelate and Thiazole Rings in a Cyclopentadienylchromium Complex”. Goh, L. Y.*; Weng, Z.; Leong, W. K. Vittal, J. J. J. Am. Chem. Soc. 2002, 124, 8804.
10. “An Organometallic Radical Route to Phosphido- and Hydrido-Phosphido-Bridged Metal–Metal Bonded Complexes of Cyclopentadienylchromiumn via Desulfurisation of Thiophosphinito Ligands”,Goh, L. Y.*; Weng, Z.; Leong, W. K.; Vittal, J. J. Organometallics 2002, 21, 5287.
11. “A Synthetic and Structural Study of Some Cyclopentadienylchromium Dithiocarbamate Complexes and Their Thermolytic Derivatives”, Goh, L. Y.*; Weng, Z.; Leong, W. K. Organometallics 2002, 21, 4398.
12. “Organometallic Radical-Initiated Carbon–Sulfur Bond Cleavage and Carbon–Carbon Coupling in Dithiocarbamate and Thiocarbenoid Cyclopentadienylchromium Complexes”, Goh, L. Y.*; Weng, Z.; Hor, T. S. A.; Leong, W. K. Organometallics 2002, 21, 4408.
13. “C-S bond Cleavage and C-C Coupling in Cyclopentadienylchromium Complexes to Give the First Dithiooxamide-Bridged and Doubly Dithiocarbamate-Bridged Double Cubanes: [Cp6Cr8S8{(C(S)NEt2)2}] and [Cp6Cr8S8(S2CNEt2)2]”. Goh, L. Y.*; Weng, Z.; Leong, W. K.; Leung, P. H. Angew. Chem. Int. Ed. 2001, 40, 3236.

专利申请:
1. 翁志强; 陈朝煌; 何伟明; 孔德道,一种经济的、稳定的三氟甲硫基化铜(I)试剂的合成,中国专利申请号:201210232795.X。
2. 翁志强; 孙兰宝; 荣明光; 白正帅,一种合成多氟芳香醚类化合物的方法,中国专利申请号:
201210390666.3。
3. 翁志强; 刘艳嫔;陈朝煌; 谭健伟, 一种稳定、高效的氟化铜(I)试剂的合成,中国专利申请号:
201310167565.4。
4. 翁志强; 陈朝煌,一种简易的、经济的卤代芳烃/烷烃三氟甲硒基化铜(I)试剂的合成方法,中国专利申请号:201310145852.5。
 

获奖情况
1. 获得2016年“Thieme Chemistry Journal Awardees”国际学术奖
2. 入选2013年福建省引进高层次创业创新人才(百人计划)
 

其他
 
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