（6月23日）Towards single crystals of covalent organic polymers/frameworks

报告人:张其春 教授

时 间：2026年6月23日下午14：00

地 点：福州大学旗山校区嘉锡楼413会议室

组织单位：福州大学化学学院

联系人及联系电话：李新雄 13635285463

报告人简介：Dr. Qichun Zhang received his B.S. at Nanjing University in China in 1992, MS in physical organic chemistry (organic solid lab) at Institute of Chemistry, Chinese Academy of Sciences in 1998, MS in organic chemistry at University of California, Los Angeles (USA, 2003), and completed his Ph.D. in chemistry at University of California Riverside in 2007. Then, he worked as a Postdoctoral Fellow at Northwestern University (Oct. 2007 –Dec. 2008). Since Jan. 2009, he joined School of Materials Science and Engineering at Nanyang Technological University (NTU, Singapore) as an Assistant Professor. On Mar 1st, 2014, he has promoted to Associate Professor with tenure. On Sep 1st 2020, he moved to Department of Materials Science and Engineering at City University of Hong Kong as a full professor. Currently, he is an associate editor of J. Solid State Chemistry & Susmat, the International Advisory Board member of Chemistry – An Asian Journal, the Advisory board member of Journal of Materials Chemistry C, the Advisory board member of Materials Chemistry Frontiers, the Advisory board member of Inorganic Chemistry Frontiers, the Advisory board member of Aggerate, the Advisory board member of Materials Advances, and the Advisory board member of Science Chinese Materials and small structures. Also, he is Guest Editors of CCS Chemistry (2020-2021), Advanced Materials (2020-2021), J Mater Chem C (2020-2021, 2017-2018), Mater. Chem Front (2019-2020), Inorganic Chemistry Frontiers (2016-2017, 2017-2018). From 2018 to 2025, he has been recognized as one of highly-cited researchers (top 1%) in Clarivate Analytics. He is a fellow of the Royal Society of Chemistry. In 2026, he won the 39th Khwarizmi International Award. Currently, his research focuses on carbon-rich conjugated materials and their applications. Till now, he has published ＞650 papers and 25 patents (H-index: 126).

张其春博士 1970 年出生，江苏高邮人。1988 年江苏省扬州中学毕业，1992 年南京大学本科分析专业毕业，1998 年中科院北京化学所物理化学硕士毕业，2003 年美国加州大学洛杉矶分校 (University of California, Los Angeles) 有机化学硕士毕业，2007 年在美国加州大学河滨分校 (University of California, Riverside)无机化学博士毕业，2007-2008 年美国西北大学(Northwestern University) 做博士后，2009 年受聘于新加坡南洋理工大学材料科学与工程学院助理教授，2014 年 3 月晋升为新加坡南洋理工大学材料科学与工程学院副教授(终身职位)，2014 年 12 月受聘于新加坡南洋理工大学数理学院副教授，2020 年 9 月受聘于香港城市大学大学材料科学与工程学院终身教授。目前，担任超金刚石及先进薄膜中心副主任。在材料科学和工程系主管博士生的招生及课程安排。

主要成果如下：

1. 作为通讯作者/一作在 J. Am. Chem. Soc. (12), Angew. Chem. Int. Ed. (38), Adv. Mater. (4), Adv. Funct. Mater. (15), Nat. Commun. (3)等期刊发表高水平文章。

2. 至今共发表 SCI 论文 635 篇，其中 JCR 一区 450 篇，高被引论文 50 篇；被引用超 50100 次；H-Index: 122 / Google-index: 130。

3. 2018-2025 年，连续 8 年 Clarivate Analytics 全球高被引作者之一； 2021-2025 年，斯坦福大学全球前 2%高被引科学家。

4. 受邀在国际会议中做主题报告或邀请报告 300 多次。

5. 主持竞争性科研项目 21 项，总金额超 8300 万港币 (含以前在新加坡项目)。

6. 2019 年入选海外高层次人才引进计划国家特聘专家。

7. 2017 年当选为 Fellow of Royal Society of Chemistry； 2026 年荣获第 39 届 Khwarizmi 国际奖。

8. 2015年担任Journal of Solid State Chemistry 副主编， 2021年任Susmat 副主编，

2016年任Journal of Materials Chemistry C, Materials Chemistry Frontiers, Inorganic Chemistry Frontiers和Chemistry-An Asian Journal顾问委员会成员； 2019年任Materials Advances 编辑委员会成员, 2020年任Aggregate 编辑委员会成员， 2023年任FlexMat, Organic Materials, Science in China: Materials和Small Structures 编辑委员会成员；担任很多杂志的客座编辑(Advanced Materials, Advanced Functional Materials, CCS Chemistry, Journal of Materials Chemistry C, Inorganic Chemistry Frontiers, Aggregate等等）。

9. 张其春教授的研究聚焦于富碳材料及其在多种器件和生物系统中的应用，具体研究方向及主要创新点包括：

(1) 首次在共价有机框架中实现压电现象;

(2) 首次使用手性共价有机框架检测手性光;

(3) 首次通过热处理构建共价有机框架自由基;

(4) 首次利用 Krohnke 氧化反应构建新型共价有机框架;

(5) 首次发现有机共晶在相变过程中表现出自愈合行为;

(6) 开发方法用于检测生物信号、肠道菌群以及微生物燃料电池;

(7) 首次通过引入分子屏障减少聚集导致淬灭效应，增强固态多环芳烃光致发光;

(8) 首次制备全有机可充电锂离子电池(单一共轭聚合物同时作为正负极);

(9) 研究还涉及有机/无机杂化材料、热电聚合物、纳米结构电极材料等，应用

于能源存储(如电池、超级电容器)、光电子器件和催化领域。

报告摘要：Covalent organic polymers/frameworks (COPs/COFs) have caused many scientists' interest in both fundamental research (synthesis, properties, theoretical simulation, etc.) and possible applications (gas absorption/separation, catalysis, energy-related devices, sensing, imaging, and so on). In this talk, I will present our recent progress on the preparation of novel COPs/COFs single crystals as well as their diverse applications in optoelectrical devices.

References:

1. Zihao Chen, Tuoya Naren, Lei Zhang, Jinglun Yang, Qianfeng Gu, Fangyuan Kang, Libao Chen*, Qichun Zhang*, “nterlocking Organic Nanotubes into A Three-Dimensional Framework: Synthesis, Crystal Structure with Dual-Buckle Configuration and Application in Stabilizing Lithium Metal Anode”, Angew. Chem. Int. Ed. 2025, 64, 10.1002/anie.202517238

2. Lizhong He+, Tuoya Naren+, Lei Zhang, Fangyuan Kang, Jinglun Yang, Zihao Chen, Aimin Yu, Dong-Sheng Li, Libao Chen*, Qichun Zhang*, “Interweaving Covalent Organic Polymer Chains into Two-Dimensional Networks: Synthesis, Single Crystal Structure and Application for Stabilizing Lithium Metal Anode”, Angew. Chem. Int. Ed. 2025, 64, e202506036.

3. Miaomiao Xue, Lei Zhang, Xin Meng, Jinglun Yang, Yanping He, Chun-Sing Lee, Jian Zhang,* Qichun Zhang*, “Ultraviolet Nonlinear Optical Single Crystals of A Three-Dimensional Chiral Covalent Framework Containing Te-O-B-O Bonds”, Angew Chem Int Ed. 2024, 63, e202412289. 10.1002/anie.202412289.

4. Lei Zhang,+ Zihao Chen,+ Xiao-Xin Li,+ Xiang Wang, Qianfeng Gu, Xin Wang, Chun-Sing Lee,* Ya-Qian Lan,* Qichun Zhang*, “A Covalent Organic Nanoribbon: Preparation, Single Crystal Structure with Chinese Luban Lock Configuration, and Photocatalytic Behavior”, Angew Chem Int Ed. 2024, 63, e202411018. 10.1002/anie.202411018

5. Qiang Dong,+ Tuoya Naren,+ Lei Zhang, Weixuan Jiang, Miaomiao Xue, Xiang Wang, Libao Chen,* Chun-Sing Lee, Qichun Zhang* “A Naphthalenetetracarboxdiimide-Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application”, Angew Chem Int Ed. 2024, 63(26), e202405426. 10.1002/anie.202405426

6. Miaomiao Xue, Lei Zhang, Xiang Wang, Qiang Dong, Zengkui Zhu, Xin Wang, Qianfeng Gu, Fangyuan Kang, Xin-Xiong Li*, Qichun Zhang,* “A Metal-Free Helical Covalent Inorganic Polymer: Preparation, Crystal Structure and Optical Properties”, Angew Chem Int Ed. 2024, 63, e202315338. 10.1002/anie.202315338

7. Miaomiao Xue‡, Lei Zhang‡, Xiao-Xin Li, Fangyuan Kang, Xiang Wang, Qiang Dong, Xin Wang, Chun-Sing Lee, Ya-Qian Lan*, Qichun Zhang,* “Growing large single crystals of covalent organic frameworks through unconventional Te-O-P linkages”, Nature Communications, 2024, 10.1038/s41467-024-54235-9

8. Lizhong He, Lei Zhang, Jinglun Yang, Fangyuan Kang, Xiang Wang, Qianfeng Gu, Lang Jiang,* Qichun Zhang*, “A Covalent Organic Polymer Containing Dative Nitrogen→Boron Bonds: Preparation, Single-Crystal Structure and Photo-Response/Photocatalytic Performance”, Small structure, 2024, 10.1002/sstr.202400492 .

9. Xin Wang,† Lei Zhang,† Xiang Wang, Tianqi Cheng, Miaomiao Xue, Qiang Dong, Yungkang Peng, Qichun Zhang*, “Constructing Covalent Organic Polymers Through Dative B-N Bonds: Synthesis, Single Crystal Structures, and Physical Properties”, Advanced Functional Materials, 2024, 10.1002/adfm.202401362.