宋秋玲

职 称: 教授

学 历: 博士研究生

硕士招生专业: 有机化学

博士招生专业: 有机化学

电子邮件: qsong@fzu.edu.cn

研究方向: 有机硼化学,有机氟化学,自由基化学

课题组网页: https://www.x-mol.com/groups/song_qiuling

教育工作经历 (Education and working experiences)

学习经历:

1994.09-1998.06,郑州大学,化学系,学士

1998.09-2001.06,北京大学,化学与分子工程学院,硕士(保送)(导师:席振峰教授)

2002.09-2006.12,美国普林斯顿大学,化学系,博士(导师:Prof. Robert A Pascal)

工作经历:

2023.3-至今,福州大学,教授

2012.11-2023.2,华侨大学,教授

2012.1-2012.11,华侨大学,副教授

2007.1-2011.12,美国制药公司,研究员/项目主管

科研简介 (Scientific research)

主要从事有机硼化学、有机氟化学、自由基化学方面的研究。目前已在Acc. Chem. Res.Chem. Soc. Rev.Nat. Chem.、Nat. Synth.ChemACS. Cent. Sci.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nat. Commun.CCS Chem.Sci. China Chem.等学术期刊论文发表论文一百余篇,详见课题组主页https://www.x-mol.com/groups/song_qiuling。

获奖情况 (awards & honors)

1994-1998,荣获郑州大学人民一等奖学金

1995-1996,1997-1998,荣获2次郑州大学徐墨耕一等奖学金

2000-2001,荣获北京大学光华奖学金

2001,荣获北京大学学术十杰优胜奖

2004,荣获中国分析测试协会二等奖

2002-2006,荣获美国普林斯顿大学Hugh Stott Taylor Merit Prize

2013年入选厦门市高层次引进人才和泉州市高级人才

2013年12月入选福建省百人计划

2014年6月入选厦门市引进重点人才

2014年被中组部选派参加在上海和瑞典举办的“中国青年科技领军人才创新能力培训”(两个月)

2014年4月入选华侨大学科技创新团队及领军人才计划之发展型团队领军人才

2015年3月入选泉州青年优秀拔尖人才及泉州“五四青年奖章”

2015年5月获得福建省“五四青年奖章”

2016年9月获得第六届中国侨界贡献奖(创新人才)

2016年9月获得华侨大学学术英才称号

2018年获得第十三届福建省自然科学优秀学术论文二等奖

2018年11月获得Asian Core Program Lectureship Award, Singapore.

2018年11月获得Asian Core Program Lectureship Award, Japan.

2019年09月获得Asian Core Program Lectureship Award, Taiwan.

2019年09月获得Asian Core Program Lectureship Award, South Korea.

2021年获得Thieme Chemistry Journals Award

2021年入选为英国皇家化学会会士(Fellow of the Royal Society of Chemistry, FRSC)

2022年获药明康德生命化学研究奖学者奖

2022年入选教育部长江学者奖励计划特聘教授

代表性论文 (Representative papers)

代表论文:

56. Copper-catalysed asymmetric hydroboration of alkenes with 1,2-benzazaborines to access chiral naphthalene isosteres, Wanlan Su, Jide Zhu, Yu Chen, Xu Zhang, Weihua Qiu, Kai Yang*, Peiyuan Yu*andQiuling Song*,Nat. Chem.2024,16, 1312-1319.

55.Enantioselective construction of C-B axially chiral alkenylborons by nickel-catalyzed radical relayed reductive coupling,Weihua Qiu,Rencai Tao,Yong He,Yao Zhou,Kai Yang* andQiuling Song*,Nat. Commun.2024,15, 10432.

54. Pd-Catalyzed B–H Aryl/Alkenylation of 1,2-Azaborines”, Zhen Zhang, Dandan Jiang, Peiwen Su, Kai Yang*, Peiyuan Yu,Qiuling Song*,ACS Catal.2024,14, 16996−17003.

53. Interception of Alkynyl Tetracoordinate Borons with Sulfur Electrophiles beyond the Zweifel Pathway, Xingxing Ma, Yuanbiao An, Luo Li, Meihui Cai,Qiuling Song*,Angew. Chem. Int. Ed.2024, e202416579.

52. Cu-catalyzed enantioselectivee assembly of axially chiral allylic boronates, Shuai Wang, Jianbo Liu, Wenyue Ma,Qiuling Song*,Sci. China Chem.,2024,doi:10.1007/s11426-024-2315-1.

51. Photo-induced decarboxylative C-S bond formation to access sterically hindered unsymmetric S-alkyl thiosulfonates and SS-alkyl thiosulfonates, Yu Guo, Guotao Lin, Mengjie Zhang, Jian Xu andQiuling Song*,Nat. Commun.2024,15,7313.

50. Fluorinating electrophilic interception in the oxidation or protonation of alkynyl tetracoordinate borons, Xingxing Ma, Zihao Zhong,Qiuling Song*,Chem,2024, doi:10.1016/j.chempr.2024.07.034.

49. Copper- and Palladium-Cocatalyzed Chemo-, Regio-, Stereo-, and Atroposelective Arylboration of 1,3-Enynes, Wangyang Li, Haohua Chen, Yanping Zheng, Yong Lu, Jinhui Xie, Shanglin Chen, Yu Lan*, andQiuling Song*ACS Catal.2024, 14, 11318−11331.

48. Chemo-, regio- and stereoselective access to polysubstituted 1,3-dienes via Nickel-catalyzed four-component reactions, Shanglin Chen, Ya-Nan Wang, Jinhui Xie, Wangyang Li , Mingxing Ye, Xingxing Ma, Kai Yang, Shijun Li, Yu Lan* andQiuling Song*,Nat. Commun.2024,15, 5479

47. Difluorocarbene-induced [1,2]- and [2,3] rearrangement of tertiary amines, Jianke Su, Yu Guo, Chengbo Li andQiuling Song*,Nat Commun.2024,15, 4794.

46. Unlocking Diverse π‑Bond Enrichment Frameworks by the Synthesis and Conversion of Boronated Phenyldiethynylethylenes, Jinhui Xie, Wangyang Li, Yong Lu, Yanping Zheng, Yanying Huang, Shanglin Chen, andQiuling Song*,J. Am. Chem. Soc.2024,146, 10167–10176.

45. N -Heterocycle-Editing to Access Fused-BN-Heterocycles via Ring-Opening/C-H Borylation/Reductive C-B Bond Formation,Xu Zhang, Wanlan Su, Huosheng Guo, Pengyuan Fang, Kai Yang* andQiuling Song*,Angew. Chem. Int. Ed.2024,63, e202318613.

44. “Ni-catalysed assembly of axially chiral alkenes from alkynyl tetracoordinate borons via 1,3-metallate shift", Xingxing Ma, Mengwei Tan, Luo Li, Zihao Zhong, Puhui Li, Jinchao Liang andQiuling Song*Nat. Chem.2024,16, 42-53.pages42–53,

43. “Palladium-Catalyzed Difluorocarbene Transfer Enabled Divergent Synthesis of γ-Butenolides and Ynones from Iodobenzene and Terminal Alkynes, Heyun Sheng, Zhiwei Chen, andQiuling Song*,J. Am. Chem.Soc.2024,146, 1722–1731.

42. "Enantio- and regioselective [2 + 2 + 2] cycloaddition of BN-diynes for construction of C-B axial chirality,Hao Wang, Bolin Qiao, Jide Zhu, Huosheng Guo, Zhen Zhang, Kai Yang*, Shi-Jun Li, Yu Lan*,Qiuling Song*,Chem2023,10, 317–329.

41. “Palladium-Catalyzed Atroposelective Kinetic C−H Olefination and Allylation for the Synthesis of C-B Axial Chirality,Jie Xu,Weihua Qiu,Xu Zhang,Zhihan Wu,Zhen Zhang,Kai Yang,Qiuling Song*,Angew. Chem. Int. Ed.2023,62, e202313388

40. “Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons”, Yu Guo, Xiaosha Wang, Chengbo Li, Jianke Su, Jian Xu* andQiuling Song*,Nat. Commun.2023,14, 5693.

39. “Transition-metal-free C(sp2)–C(sp3) cross-coupling of α-(pseudo)halo aliphatic ketones with boronic acids via a 1,4-metallate shift”, Xue Li, Haohua Chen, Hao Wang, Qiaohui Zhang, Heyun Sheng, Yu Lan* andQiuling Song*,Nat. Synth.2023,2, 1211-1221.

38. “Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron”, Kai Yang, Yanfei Mao, Zhihan Zhang, Jie Xu, Hao Wang, Yong He, Peiyuan Yu* andQiuling Song*,Nat. Commun.2023,14, 4438.

37. “Cu(I)-Catalyzed Highly Diastereo- and Enantioselective Constructions of Boron/Carbon Vicinal Stereogenic Centers via Insertion Reaction”,Guan Zhang, Xinping Cai, Junyi Jia, Bofan Feng, Kai Yang, andQiuling Song*,ACS Catal.2023,13, 9502-9508.

36. “Unconventional Transformations of Difluorocarbene with Amines and Ethers”, Xingxing Ma, Jianke Su andQiuling Song*,Acc. Chem. Res.2023,56, 592-607.

35. “Modular Assembly of Versatile Tetrasubstituted Alkenyl Monohalides from Alkynyl Tetracoordinate Borons”, Xingxing Ma, Luo Li, Mengwei Tan, Zihao Zhong, Jinchao Liang, Puhui Li andQiuling Song*,Chem,2023, doi: 10.1016/j.chempr.2023.01.005.

34. “Construction of Axially Chiral Alkenylboronates via Cu/Pd Dual Catalysis-Promoted Atroposelective Arylboration of Alkynes”, Wangyang Li, Shanglin Chen, Jinhui Xie, Zhenwei Fan, Kai Yang andQiuling Song*,Nat. Synth.2023,2, 140-151.

33. “Deaminative Arylation or Alkenylation of Aliphatic Tertiary Amines with Aryl or Alkenylboronic Acids via Nitrogen Ylides”, Jianke Su, Chengbo Li, Xinyuan Hu, Yu Guo andQiuling Song*,Angew. Chem. Int. Ed.2022,61, doi: 10.1002/anie.202212740.

32. “Enantioselective Copper-Catalyzed sp2/sp3 Diborylation of 1,1-Chloro-Trifluoromethyl– 2-alkenes”, Zhenwei Fan, Mingxing Ye, Yahao Wang, Jian Qiu, Wangyang Li, Xingxing Ma, Kai Yang andQiuling Song*,ACS Cent. Sci.2022,8, doi: 10.1021/acscentsci.2c00339.

31. “Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes”, Shengnan Jin, Jinxia Li, Kang Liu, Wei-Yi Ding, Shuai Wang, Xiujuan Huang, Xue Li, Peiyuan Yu andQiuling Song*,Nat. Commun.2022,13, 3524-3536.

30. “Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction”, Guan Zhang, Zhihan Zhang, Mengyuan Hou, Xinping Cai, Kai Yang, Peiyuan Yu* andQiuling Song*,Nat. Commun.2022,13, 2624-2635.

29. “Photo-induced trifunctionalization of bromostyrenes via remote radical migration reactions of tetracoordinate boron species”, Chaokun Li, Shangteng Liao, Shanglin Chen, Nan Chen, Feng Zhang, Kai Yang andQiuling Song*,Nat. Commun.2022,13, 1748-1760.

28. “Enantioselective Cobalt-Catalyzed Cascade Hydrosilylation and Hydroboration of Alkynes to Access Enantioenriched 1,1-Silylboryl Alkanes”, Shengnan Jin, Kang Liu, Shuai Wang, andQiuling Song*,J. Am. Chem. Soc.2021,143, 13124-13134.

27. “Difluorocarbene enables to access 2-fluoroindoles fromortho-vinylanilines”, Jianke Su, Xinyuan Hu, Hua Huang, Yu Guo andQiuling Song*,Nat. Commun.2021,12, 4986-4996.

26. “Construction of Axially Chiral Arylborons via Atroposelective Miyaura Borylation”, Kai Yang, Yanfei Mao, Jie Xu, Hao Wang, Yong He, Wangyang Li andQiuling Song*,J. Am. Chem. Soc.2021,143, 10048–10053.

25. “Tetracoordinate Boron Intermediates Enabled Unconventional Transformations”, Kai Yang andQiuling Song*,Acc. Chem. Res.,2021, 54, 2298–2312.

24. “Elemental sulfur enabled divergent synthesis of disulfides, diselenides and polythiophenes from β-CF3-1,3-enynes”, Shengnan Jin, Shi-Jun L, Xingxing Ma, Jianke Su, Haohua Chen, Yu Lan* andQiuling Song*,Angew. Chem. Int. Ed.2021,60, 881-888.

23. “Recent Progress on Selective Deconstructive Modes of Halodifluoromethyl and Trifluoromethyl-containing Reagents”, Xingxing Ma andQiuling Song*,Chem. Soc. Rev.,2020,49, 9197-9219.

22. “Cu-catalyzed regio- and stereodivergent chemoselectivesp2/sp31,3-and 1,4-diborylations of CF3-containing 1,3-enynes”, Zhijie Kuang, Haohua Chen, Jian Qiu, Zongliang Ou, Yu Lan*andQiuling Song*,Chem,2020,6, 2347-2363.

21. “Deconstructive Functionalizations of Unstrained Carbon−Nitrogen Cleavage Enabled by Difluorocarbene”, Jianke Su, Xingxing Ma, Zongliang Ou,Qiuling Song*,ACS Cent. Sci.2020,6, 1819-1826.

20. “Passerini-Type Reaction of Boronic Acids Enablesα-Hydroxyketones”, Kai Yang, Feng Zhang, Tongchang Fang, Chaokun Li, Wangyang Li, andQiuling Song*,Nat. Commun.2020,12, 441-450.

19. “Design, Synthesis, and Applications of ortho-Sulfur Substituted Arylphosphanes”, Yu Guo, Ying Luo, Shiqiang Mu, Jianke Su, Jian Xu andQiuling Song*,CCSChem.2022, DOI:10.31635/ccschem.022.202201944.

18. “Deconstructive Difunctionalizations of Carbon-Oxygen Cleavage in Cyclic Ethers Enabled by Difluorocarbene to Access Difluoromethyl Ethers”, Heyun Sheng, Jianke Su, Xue Li and Qiuling Song*,CCS Chem.2022, DOI: 10.31635/ccschem.022.202101576.

17. “Atom Recombination of Difluorocarbene Enables 3-Fluorinated Oxindoles from 2-Aminoarylketones”. Guan Zhang , Qianqian Shi , Mengyuan Hou , Kai Yang , Shihui Wang , Shuai Wang , Wangyang Li , Chaokun Li , Jian Qiu , Hetao Xu , Lu Zhou , Cece Wang , Shi-Jun Li , Yu Lan* , andQiuling Song*,CCS Chemistry.2021,3, 1613–1621.

16. “Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides”, Qiang Feng, Xingxing Ma, Wen Bao, Shi-Jun Li, Yu Lan*, andQiuling Song*,CCS Chemistry.2021,3, 377-387.

15. “Palladium-catalyzed Three-component Synthesis of Phosphine-containing Tetrasubstituted Acyclic Unsymmetric Allcarbon Olefins”, Xingxing Ma, Puhui Li, Jinchao Liang, Hejun An, Kai Yang, and Qiuling Song *,Cell Rep. Phy. Sci.2020,2, 100629-100641.

14. “Transition-Metal-Free Double Insertive Coupling of Isocyanides with Arylboronic Acids Enabled Diarylmethanamines”, Kai Yang, Xiaoxiao Hu, Wangyang Li,Jian Qiu, Qiang Feng, Shihui Wang, Guan Zhang, Zhijie Kuang, Peiyuan Yu*andQiuling Song*,Cell Rep. Phy. Sci.2020,1, 100268-100283.

13. “Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides”, Shaoyu Mai, Wendong Li, Xue Li, Yingwei Zhao,Qiuling Song*,Nat. Commun.2019,10, 5709-5731.

12. “Michael Reaction Inspired Atroposelective Construction of Axially Chiral Biaryls”, Shengyi Yan, Wang Xia, Shaoyu Li,Qiuling Song*, Shaohua Xiang, Bin Tan*,J. Am. Chem. Soc.2020,142, 7322-7327.

11. “Chiral Brønsted Acid from Chiral Phosphoric Acid Boron Complex and Water: Asymmetric Reduction of Indoles” Kai Yang,Yixian Lou, Chenglan Wang, Liang-Wen Qi, Tongchang Fang, Feng Zhang, Hetao Xu, Lu Zhou, Wangyang Li, Guan Zhang, Peiyuan, Yu*,Qiuling Song*,Angew. Chem. Int. Ed.2020,59, 3294-3299.

10. “Stereospecific 1,4-Metallate Shift Enables Stereoconvergent Synthesis of Ketoximes”, Kai Yang, Feng Zhang, Tongchang Fang, Guan Zhang,Qiuling Song*,Angew. Chem. Int. Ed.2019,58, 13421-13426.

9. “Divergent Synthesis of Disulfanes and Benzenesulfonothioates Bearing 2-Aminofurans From N-Tosylhydrazone-Bearing Thiocarbamates”, Shaoyu Mai andQiuling Song*,Angew. Chem. Int. Ed.2017,56, 7952-7957.

8. “Radical-Induced 1,2-Boron Shift, Enabling 1,3-Difunctionalization of Allylboronic Esters”, Kai Yang, Zhijie Kuang,Qiuling Song*,Chem2020,6, 330-331.

7. “Design and Applications of Highly Stereoselective 1, 3-Dienes Aldehydes or Ketones”, Qiang Feng, Shihui Wang, Xingxing Ma, Changqing Rao and Qiuling Song*,Sci. China. Chem.2022, doi:10.1007/s11426-021-1204-5.

6. “C-F bond activation under transition-metal-free conditions”, Han-Jun Ai, Xingxing Ma,Qiuling Songand Xiao-Feng Wu*,Sci. China Chem.2021,64, 1630-1659.

5. “Base-catalyzed Diborylation of Alkynes: Synthesis and Applications of cis-1,2-Bis(boryl)alkenes”, Zhijie Kuang, Guoliang Gao andQiuling Song*,Sci. China Chem.2020,62, 62-66.

4. “Base-Catalyzed Highly Diastereoselective Deuteration of Diarylethynes via Domino-Borylation-Protodeboronation”, Zhijie Kuang, Shaoyu Mai, Kai Yang andQiuling Song*,Sci. Bull.,2019,22, 1685-1690.

3. “Enantio- and Diastereoselective Diarylmethylation of 1,3-Dicarbonyl Compounds”, Xin Li, Songtao He andQiuling Song*,Chem. Sci.2020,11,5969-5973.

2. “S8-Catalyzed Triple Cleavage of Bromodifluoro Compounds for the Assembly of N-containing Heterocycles”, Shuilin Deng, Haohua Chen, Xingxing Ma, Yao Zhou, Kai Yang, Yu Lan*, andQiuling Song*,Chem. Sci.2019,10, 6828-6833.

1. “Four-Coordinate Triarylborane Synthesis via Cascade B-Cl/C-B Cross-Metathesis and C-H Bond Borylation”, Kai Yang, Guan Zhang andQiuling Song*,Chem. Sci.2018,9,7666-7672.

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