教育工作经历

2025.07-迄今  福州大学，校聘教授

2020.08-2025.07 福州大学，副教授，硕/博导

2018.06-2020.08 中国科学院大学福建物质结构研究所，博士后（合作导师：郭国聪&王明盛）

2013.09-2018.06 中国科学院大学福建物质结构研究所，理学博士（导师：郭国聪&王明盛）

2010.09-2011.07 兰州大学，交流生                             

2009.09-2013.06 山东大学，理学学士  

教学简介

讲授化学学院本科生《波谱学》、《单晶结构分析》、《物理化学实验》课程；研究生《高级物理化学实验》课程。

科研简介

光致变色材料具有颜色和性质转变双重特点，是一类具有广泛应用前景的智能材料。然而，响应速度慢、着色态稳定难等变色性能不足，以及性质转变调控难等瓶颈制约了这类材料的应用。针对这些问题，提出D-f-A电子转移、着色态稳定新机制，优化变色性能；提出周期场导向序构组装、模型导向序构筛选新方法，实现电学性质精准调控；在此基础上，拓展了仿生变色催化剂和智能电路保护等新应用。近年来已在相关领域发表SCI论文50余篇，其中第一/通讯作者论文27篇，包括 J. Am. Chem. Soc.（1篇）、 Angew. Chem. Int. Ed.（6篇）、 Nat. Commum. (2篇)、CCS Chem.（1篇）等。

目前的研究兴趣是：

[1] 刺激响应金属氧簇晶态/膜材料的合成和应用

（物理刺激：光致变色、热致变色、电致变色；化学刺激：离子捕获、气敏传感）

[2] 电子转移、离子迁移、分子间相互作用的理论研究

项目

Scientific research projects after jion Fuzhou Uninversity:

[1] 无机-有机杂化多铌氧酸簇聚物的光致变色性质的探索，青年科学基金项目（22001037），2021-2023

[2] 紫精基多铌氧酸簇聚物的光致变色性质的探索，福州大学贵重仪器设备开放测试基金(2021T004)，2021-2021

[3] 光致变色功能的杂化多铌氧酸簇聚物的性能优化，福州大学科研启动经费（511002），2021-2022

[4] 光致变色电荷转移复合物的设计合成和导电开关研究，福建省自然科学青年创新项目（2021J05111），2021-2024

[5] 无机-有机杂化多钽氧酸簇聚物的光致变色性质的探索，结构化学国家重点实验室开放基金，2022-2024

[6] 穴状多铌氧簇基框架材料富集放射性离子的研究，面上项目（22371045），2024-2027

Scientific research projects before jion Fuzhou Uninversity:

[1] 光致变色材料和智能器件，中国博士后创新人才计划（BX20180304），2018-2020

[2] 室温光致变色介电开关材料的研究，中国博士后面上基金（2018M642580），2018-2020

[3] 电子转移光致变色半导体的结构设计和导电调制研究，结构化学国家重点实验室优秀青年项目，2019-2020

论文

Publications after jion Fuzhou Uninversity:

[20] Zheng-Wei Guo,^† Yan-Huang Yan,^† Yi Chen, Yi-Ying Li, Xin-Xiong Li, Cai Sun* and Shou-Tian Zheng* An All-Inorganic Three-Dimensional Polyoxoniobate Framework with ppb-Level Chemiresistive Sensing for Ammonia, Nat. Commun. 2025, 16, 6379

[19] Cai Sun,^† Jian-Ping Chen,^† Yan-Lan Wu,^† Yi-Ying Li, Xin-Xiong Li, Ping-Wei Cai,* Carsten Streb,* and Shou-Tian Zheng* Single-Crystal-to-Single-Crystal Transformation in a Thermally Stable All-Inorganic Polyoxoniobate Framework Boosts Lithium Ion Battery Anode Performance, Angew. Chem. Int. Ed. 2025, 64, e202506533

[18] Yan-Ru Li, Chun-Xia Chen, Ke-Xin Qi, Cai Sun* and Shou-Tian Zheng* Development of an integrated polyoxoniobate catalyst with oxygen activation and basicity as a green catalyst for efficient aerobic oxidation of aldehydes at room temperature, Green Chem., 2025, 27, 7781-7787

[17] Chun-Xia Chen, Shui-Lin Duan, Xiao-Yue Zhang, Rong-Zhi Sun, Ping-Wei Cai, Cai Sun* and Shou-Tian Zheng* Organic-Inorganic Hybrid Co-Containing Polyoxoniobates as Hydrogen Evolution Catalyst in Alkaline Media, Dalton Trans. 2025, 54, 3591

[16] Yi-Xin Liu,† Ping-Xin Wu,† Jing-Yi Dai, Ping-Wei Cai, Cai Sun* and Shou-Tian Zheng*, Site differentiation strategy for selective strontium uptake and elution within an allinorganic polyoxoniobate framework, Nat. Commun. 2024, 15, 8896

[15] Zhe-Hong Chen（本科生）,† Xiao-Yue Zhang,† Da-Huan Li, Xin-Xiong Li, Yan-Qiong Sun, Cai Sun* and Shou-Tian Zheng*, Organic-inorganic hybrid Co-containing polyoxotungstate as an oxygen evolution catalyst, CrystEngComm. 2024,26,5840

[14] Lei Jia, Yi-Xin Liu, Xin-Xiong Li, Cai Sun,* and Shou-Tian Zheng* A Palladium-Containing Polyoxotungstate with Anisotropic Proton Conductivity, Inorg. Chem. 2024, 63, 14308-14312

[13] Jin-Ai Fan,† Hao Yu,† Yu-Diao Lin, Ming-Qiang Qi, Xiang-Jian Kong, Cai Sun* and Shou-Tian Zheng*, An organophosphate 3d-4f heterometallic polyoxoniobate nanowire, Nanoscale, 2024, 16, 12420-12423

[12] Ya-Kun Zuo, Yan-Ru Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun* and Shou-Tian Zheng*, Efficient catalysis of Knoevenagel condensation by 1D coppercontaining heterpolyoxoniobate at room temperature, Inorg. Chem. Front. 2024, 11，1993-1997

[11] Xiao-Yue Zhang, Jin-Ai Fan, Zhe-Hong Chen, Cai Sun* and Shou-Tian Zheng*, The Formation Reason of Intermolecular Charge Transfer bands: A series of Polyoxomolybdates as a Case Study, Dalton Trans. 2024, 53，6162-6167

[10] Qiu-Pei Qin, Jian Lu, Cai Sun*, Ming-Sheng Wang,* and Guo-Cong Guo*, Design Strategy for Improving Detection Sensitivity in a Bromoplumbat Photochromic Semiconductor, Small 2024,20，2307333

[9] Da-Huan Li,+ Xiao-Yue Zhang,+ Jiang-Quan Lv, Ping-Wei Cai, Yan-Qiong Sun, Cai Sun* and Shou-Tian Zheng*, Photo-Activating Biomimetic Polyoxomolybdate for Boosting Oxygen Evolution in Neutral Electrolytes Angew. Chem. Int. Ed. 2023, 62, e202312706

[8] Hao Yu,+ Yu-Diao Lin,+ Shu-Lin Huang, Xin-Xiong Li, Cai Sun* and Shou-Tian Zheng*, Photochromic Polyoxoniobates with Photoinduced "D-f-A" Electron Transfer Mechanism, Angew. Chem. Int. Ed. 2023, 62, e202302111

[7] Zheng-Yi Liu（本科生）,+ Jian-Ping Ye,+ Yi-Lun Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun* and Shou-Tian Zheng*, Cadmium-containing windmill-like heteropolyoxoniobate macrocycle with high yield for catalyzing Knoevenagel condensation, Dalton Trans., 2023, 52, 1193-1197

[6] Ping-Xin Wu, Zheng-Wei Guo, Rong-Da Lai, Xin-Xiong Li, Cai Sun,* and Shou-Tian Zheng*, Giant Polyoxoniobate-Based Inorganic Molecular Tweezers: Metal Recognitions, Ion-Exchange Interactions and Mechanism Studies, Angew. Chem. Int. Ed. 2023, 62, e202217926

[5] Peng-Hao Wang, Xiao-Yue Zhang, Jin-Ai Fan, and Cai Sun*, Unveiling the effect of water on photoinduced electron transfer by crystallographic study, Chem. Commun., 2022, 58, 13099-13102

[4] Peng-Hao Wang, Bin-Wen Liu, Guo-Qiang Wang, and Cai Sun*, Photochromic Semiconductors: Bottom-Up Strategy to Construct Type II-Stacking Viologen π‑Aggregates, Inorg. Chem. 2022, 61, 17196−17201

[3] Cai Sun, Chen Yang, Pei-Xin Li, Ming-Sheng Wang,* and Guo-Cong Guo*, Photoswitching Bulk Quadratic Nonlinear-Optical Properties with Record Contrast in a Photochromic Semiconductor, Inorg. Chem. 2021, 60(13), 9278−9281.

[2] Cai Sun, Ming-Sheng Wang,* and Guo-Cong Guo*, Photochromic Semiconductors with Record-High Dielectric Permittivity Gain at Room Temperature, ACS Appl. Electron. Mater. 2021, 3(8), 3301−3305.

[1] Xiu-Shuang Xing,⁺ Cai Sun,⁺ Lu Liu, Ming-Sheng Wang* and Guo-Cong Guo, Light-Responsive Proton Conductor: Record High Gain of Proton Conductivity Achieved by Photoinduced Electron-Transfer Strategy, CCS Chem. 2021, 3, 50-57.

Publications before jion Fuzhou Uninversity:

[7] Guan-E Wang,⁺ Cai Sun,⁺ Ming-Sheng Wang* and Guo-Cong Guo*. Semiconducting crystalline inorganic–organic hybrid metal halide nanochains, Nanoscale, 2020, 12, 4771-4789.

[6] Cai Sun⁺, Xiao-Qing Yu⁺, Ming-Sheng Wang,* and Guo-Cong Guo. A Smart Photochromic Semiconductor: Breaking the Intrinsic Positive Relation Between Conductance and Temperature, Angew. Chem. Int. Ed. 2019, 58, 9475-9478.

[5] Cai Sun, Ming-Sheng Wang,* and Guo-Cong Guo*. Covalently Bonded Pillared Layered Bromoplumbate with High Thermal Stability: High Capacitance Gain after Photoinduced Electron Transfer, ACS Appl. Mater. Interfaces 2019, 11, 30713-30718.

[4] Cai Sun, Gang Xu, Xiao-Ming Jiang, Guan-E Wang, Pei-Yu Guo, Ming-Sheng Wang,* and Guo-Cong Guo*, Design Strategy for Improving Optical and Electrical Properties and Stability of Lead Halide Semiconductors, J. Am. Chem. Soc. 2018, 140, 2805-2811.

[3] Cai Sun, Ming-Xiu Du, Jian-Gang Xu, Fei-Fei Mao, Ming-Sheng Wang,* and Guo-Cong Guo, A Nanowire Array with Two Types of Bromoplumbate Chains and High Anisotropic Conductance, Dalton Trans. 2018, 47, 1023-1026.

[2] Cai Sun, Ming-Sheng Wang,* Pei-Xin Li, and Guo-Cong Guo*, Conductance Switch of a Bromoplumbate Bistable Semiconductor by Electron-Transfer Thermochromism, Angew. Chem. Int. Ed. 2017, 56, 554-558.

[1] Cai Sun, Ming-Sheng Wang,* Xian-Zhang, Ning-Ning Zhang, Lin-Rong Cai and Guo-Cong Guo*, Viologen-templated bromoplumbate: a new in situ synthetic method and energy gap engineering, CrystEngComm. 2017, 19, 4476-4479.

获奖

2018年 获中国科学院院长优秀奖；

2018年 获卢嘉锡优秀研究生奖；

团队成员

职位信息

郑寿添教授（长江）团队常年招收具有化学、物理等背景博士后，待遇优厚。

办公室位置

福州大学孟超楼（7号楼）208c。

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