姓    名:廖赛虎
职    称:教授 (博士生导师)  
学    历:博士
办公室:化学学院嘉锡楼503
电    话:+86-130-43548506
专    业:有机化学,高分子化学
电子邮箱:shliao at fzu.edu.cn
研究方向:有机催化,光催化有机合成,光催化聚合

课题组网站:http://www.liao-lab.com; https://www.x-mol.com/groups/liaogroup   


教育工作经历

教育背景:

  2001-2005:华中科技大学化学系,学士  

  2005-2007:华中科技大学化学系,硕士,导师:龚跃法教授  

  2007-2011:德国马克斯-普朗克煤炭研究所,博士,导师:Prof. Dr. Benjamin List

工作经历:
  2011-2013:中科院上海有机化学研究所,助理研究员,导师:唐勇研究员  

  2013-2016:德国马普煤炭研究所,博士后,导师:Prof. Dr. Benjamin List 

  2016-2019:福州大学化学学院,“闽江学者”特聘教授

  2017.09-至今:福州大学化学学院,教授


教学简介

   有机化学

科研简介

      主要从事有机催化、光催化有机合成、高分子合成等方面工作,先后参与及主持多个科研项目。迄今为止,已在 Acc. Chem. Res., Nat. Commun., J. Am. Chem. Soc., Angew. CHem. Int. Ed. 等国际著名学术期刊上发表论文四十余篇;研究工作受到国际同行积极评价,多篇论文被"NatureChemistry"、"Synform"、"SynFacts"等杂志作为亮点评述。参与编写外文书籍2部,申请中国专利5项,国际专利1项并已获多项授权,另撰写SynFacts评论文章40余篇。2016年入选福建省“闽江学者”特聘教授, 2017年入选海外高层次人才项目,2018年入选高校青年拔尖人才后备项目以及福建省“百人计划”。

     目前主要研究领域:有机催化,光催化有机合成,光催化高分子合成,手性聚合物等。

     课题组常年招收硕士研究生、博士研究生、科研助理和博士后。

     热诚欢迎对有机化学和高分子感兴趣,有科研热情和梦想的同学加入我们!

     一起共筑精彩化学!


社会兼职

    有机合成与功能福建省高校重点实验室主任


科研项目

   1.  福建省百人计划

   2.  高校青年拔尖人才后备人才 

   3.  海外高层次人才项目 

   4.  国家自然科学基金项目青年基金 

   5.“闽江学者”特聘教授科研启动基金


代表性论文


2020:

8. Qiang Ma, Jinshuai Song, Xun Zhang, Yu Jiang, Li Ji, Saihu Liao,* Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight, Nat. Commun. 2020, accepted, DOI: 10.21203/rs.3.rs-89454/v1 PDF

7. Xingliang Nie, Tianxiao Xu, Jinshuai Song, Anandkumar Devaraj, Bolun Zhang, Yong Chen,  Saihu Liao,* Radical Fluorosulfonylation: Accessing Alkenyl Sulfonyl Fluorides from Alkenes, Angew. Chem. Int. Ed. 2020, DOI: 10.1002/anie.202012229. PDF

6. Tianpeng Cao, Tianxiao Xu, Ruting Xu, Xianli Shu, Saihu Liao,* Decarboxylative thiolation of redox-active esters to free thiols and further diversification, Nat. Commun. 2020, 11:5340. PDF

5. Xianli Shu, Ruting Xu, Qiang Ma and Saihu Liao,* Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters, Org. Chem. Front. 2020, 7, 2003–2007. PDF

4. Xun Zhang, Siping Hu, Qiang Ma, and Saihu Liao,* Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules, Polym. Chem. 2020, 11, 3709–3715. PDF

3. Tianxiao Xu, Tianpeng Cao, Mingcheng Yang, Ruting Xu, Xingliang Nie, and Saihu Liao,* Decarboxylative Thiolation of Redox-Active Esters to Thioesters by Merging Photoredox and Copper Catalysis, Org. Lett. 202022, 3692–3695  PDF

2. Tianxiao Xu, Tianpeng Cao, Qingyuan Feng, Shenlin Huang,* and Saihu Liao,* Metal-free dehydrosulfurization of thioamides to nitriles under visible light, Chem. Commun., 2020, DOI:10.1039/d0cc01380c. PDF

1. Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, Qinggang Wang, and Saihu Liao,* Imidodiphosphorimidate (IDPi) as an Efficient Organocatalyst for Controlled/Living Ring-Opening Polymerization of Lactones, Eur. Polym. J. 2020, 123: 109449. PDF


2019: 

6. Qiang Ma, Xun Zhang, Li Ji, Saihu Liao,* BINOLs as Visible Light Photocatalyst for Metal-Free Atom Transfer Radical Polymerization, Polym. Chem. 2019, 10, 6662-6668. PDF

5. Mingcheng Yang, Tianpeng Cao, Tianxiao Xu, Saihu Liao,* Visible-Light-Induced Deaminative Thioesterification of Amino Acid Derived Katritzky Salts via Electron Donor–Acceptor Complex Formation, Org. Lett. 2019, 21, 8673–8678.

4. Rongbiao Wei, Liang Ge, Hongli Bao, Saihu Liao,* Yajun Li,* Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides, Synthesis, 2019, 51, 4645–4649.

3. Ruting Xu, Tianxiao Xu, Mingcheng Yang, Tianpeng Cao, Saihu Liao,* A Rapid Access to Aliphatic Sulfonyl Fluorides, Nat. Commun. 2019, 10, 3752.

2. Li Ji, Jia-Shuai Liu, Xiao-Yan Wang, Jun-Fang Li, Zhou Chen, Saihu Liao,* Xiu-Li Sun,* Yong Tang, An Efficient and Mild Route to Highly Fluorinated Polyolefins via Copolymerization of Ethylene and 5-Perfluoroalkylnorbornenes, Polym. Chem. 2019, 10, 3604–3609

1. Zhu Cao, Jian-Bo Zhu, Lijia Wang,* Saihu Liao,* Yong Tang, A Synthesis of Multifunctionalized Indoles from [3 + 2] Annulation of 2‑Bromocyclopropenes with Anilines, Org. Lett. 2019, 21, 4097–4100.


2018

1. Hai-Xian Gong, Zhu Cao, Saihu Liao, Mei-Jin Lin*, Photoexcited Perylene Diimide Radical Anions for the Reduction of Aryl Halides: A Bay-substituent Effects, Org. Chem. Front. 2018, 5, 2296–2302.


Selected publications before 2017:

10. Saihu Liao, Markus Leutzsch, Mattia Riccardo Monaco, Benjamin List*, Catalytic Enantioselective Conversion of Epoxides to Thiiranes, J. Am. Chem. Soc. 2016, 138, 5230–5233. (Highlighted by Nature Chemistry and SynFacts)

9. Saihu Liao, Xiu-Li Sun, Yong Tang*, Sidearm Strategy for Catalyst Design Based on Bisoxazolines in the Remote Control of Enantioselection and Related, Acc. Chem. Res. 2014, 47, 2260–2272.

8. Pan Wang, Wen-Jie Tao, Xiu-Li Sun, Saihu Liao* and Yong Tang*, A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis, J. Am. Chem. Soc. 2013, 135, 16849–16852. (Highlighted by SynFacts)

7. Jian-Bo Zhu, Peng Wang, Saihu Liao*, and Yong Tang*, Ylide Hydrolysis in Tandem Reactions: A Highly Z/E-Selective Access to 3-Alkylidene Dihydrobenzofurans and Related Analogues, Org. Lett. 2013, 15, 3054–3057.

6. Jian-Bo Zhu, Peng Wang, Saihu Liao* and Yong Tang*, PPh3-mediated Intramolecular Conjugation of Alkyl Halides with Electron-deficient Olefins: Facile Synthesis of Chromans and Relevant Analogues, Chem. Commun. 2013, 49, 4570–4572.

5. Saihu Liao, Peng Wang, Yong Tang, “Covalent Activations: Ylides” in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications, P. Dalko, Ed., Wiley-VCH & Sons: Weinheim, Germany, 2013. (Book Chapter)

4. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation, Adv. Syn. Catal. 2012, 354, 2363–2367.

3. Benjamin List and Saihu Liao, “The Proline-Catalyzed Mannich Reaction and the Advent of Enamine Catalysis”, in Organic Chemistry–Breakthroughs and Perspectives,K. Ding, L.-X. Dai, Eds., Wiley-VCH: Weinheim, Germany, 2012. (Book Chapter)

2. Saihu Liao, Ilija Čorić, Qinggang Wang, and Benjamin List*, Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation, J. Am. Chem. Soc. 2012, 134, 10765–10768. (Highlighted by SynFacts)

1. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidationof Alkenes with Manganese(III)-Salen Phosphate Complexes, Angew. Chem. Int. Ed. 2010, 49, 628–631. (“Hot Paper”, highlighted by SynFacts)


获奖情况

2018年入选福建省“百人计划

2018年入选福建省高校青年拔尖人才(领军人才后备)项目

2017年入选国家海外高层次人才青年项目

2016年入选福建省“闽江学者”特聘教授


其他

 ***诚聘有机化学或高分子方向博士后和科研助理各2名,待遇从优,有意请发简历至shliao at fzu.edu.cn

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